Inducing tilted parallel alignment in liquid crystals

Stock material or miscellaneous articles – Liquid crystal optical display having layer of specified... – With charge transferring layer of specified composition

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359 78, 359 79, 359 82, 359 87, 359106, C09K 1900

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055298176

ABSTRACT:
A substrate is treated prior to use to induce a near-parallel orientation of a liquid crystal director relative to the substrate. A layer of silica is deposited on the substrate by in-line magnetron sputtering as the substrate is moved past the sputtering target, and the silica-coated substrate is thereafter treated with an alcohol that is selected from one of two classes of alcohols: (1) alcohols having an aromatic ring structure on one end of an aliphatic chain and a hydroxy group on the other end, with or without at least one ether group in the chain, and (2) an aliphatic chain having a hydroxy group at one end and at least one ether linkage in the chain. An example is 2-phenylethanol. The alcohol-treated substrate is covered with a layer of the liquid crystal. The process of the invention induces a tilt to the director of the liquid crystal. The tilt is about 0.5.degree. to 4.degree., as measured parallel to the surface of the substrate.

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W. P. Bleha, "Progress in Liquid Crystal Light Valves", Laser Focus/Electro-Optics, pp. 111-120 (Oct. 1983).
J. L. Janning, "Thin film surface orientation for liquid crystals", Applied Physics Letters, vol. 21, pp. 173-174 (1972).

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