Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1975-11-14
1977-08-02
Garvin, Patrick P.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
526187, C08F 466, C08F 468
Patent
active
040394727
ABSTRACT:
The particle size of as formed polyethylene or ethylene copolymer containing up to about twenty percent of a C.sub.3 to C.sub.8 olefin can be increased by using a high yield, solid catalyst component prepared from (1) a magnesium alkoxide, (2) a titanium (IV) or vanadium (V) chloride, chloroalkoxide or alkoxide, (3) an alkylaluminum compound, and (4) hydrogen chloride. The particle size of as formed polymer can be increased substantially using the hydrogen-chloride-prepared catalyst component, compared to the particle size of polymer made using a similar catalyst component prepared without the use of hydrogen chloride, when either is employed with an alkylaluminum compound promoter in a slurry or vapor phase polymerization process at moderate polymerization temperatures and pressures.
REFERENCES:
patent: 3392159 (1968-07-01), Schooley et al.
patent: 3489729 (1970-01-01), Kahle et al.
patent: 3644318 (1972-02-01), Diedrich et al.
patent: 3658722 (1972-04-01), Delboville et al.
patent: 3951935 (1976-04-01), Engelmann
Garvin Patrick P.
Gilkes Arthur G.
McClain William T.
Riley Reed F.
Standard Oil Company (Indiana)
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