Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1977-08-25
1978-08-08
Smith, Edward J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
252431R, 526352, 526907, C08F 402, C08F 1002
Patent
active
041058461
ABSTRACT:
The particle size of as formed polyethylene or ethylene copolymer containing up to about fifteen percent of a C.sub.3 to C.sub.8 olefin, which is made using a promoted solid catalyst component prepared from a magnesium alkoxide, a titanium (IV) alkoxide and an alkylaluminum dichloride, is increased by adding the dichloride in at least two stages and allowing the preparation mixture to age between stages during the preparation of said catalyst component. The particle size of polymer can be increased substantially using the so treated catalyst component, compared to the particle size of polymer made using untreated catalyst component, when either catalyst component is employed together with an alkylaluminum compound promoter in a slurry or vapor phase process at moderate polymerization temperature and pressure.
REFERENCES:
patent: 3901863 (1975-08-01), Berger et al.
Boone David E.
Fotis, Jr. Peter
Hoff Glen R.
Gilkes Arthur G.
McClain William T.
Riley Reed F.
Smith Edward J.
Standard Oil Company (Indiana)
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