Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1994-08-31
1996-08-27
Beck, Shrive
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585502, 585510, 585521, C07C 214
Patent
active
055503071
ABSTRACT:
An oligomer is made by contacting an olefinic monomer with a catalyst comprising boron trifluoride, an alcohol alkoxylate, and a ketone. In one embodiment, the olefinic monomer is a straight-chain, .alpha.-olefinic monomer containing from 8 to 12 carbon atoms, the alcohol alkoxylate is 2-ethoxyethanol, the ketone is methyl ethyl ketone, and the oligomer product has a kinematic viscosity at 100.degree. C. of less than 1.7 cSt. Before removal of unreacted monomer, the oligomer product is at least 50 wt. % dimer, at least 80 wt. % dimer plus trimer, and less than 3.25 wt. % tetramer and greater.
REFERENCES:
patent: 4436947 (1984-03-01), Morganson et al.
patent: 5068487 (1991-11-01), Theriot
patent: 5095172 (1992-03-01), Lanier et al.
patent: 5420373 (1995-05-01), Hope et al.
Cupples Barrett L.
Ho Ting C.
Hope Kenneth D.
Beck Shrive
Chevron Chemical Company
Meeks Timothy H.
Schaal E. A.
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