Increased dimer yield of olefin oligomers through catalyst modif

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585502, 585510, 585521, C07C 214

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active

055503071

ABSTRACT:
An oligomer is made by contacting an olefinic monomer with a catalyst comprising boron trifluoride, an alcohol alkoxylate, and a ketone. In one embodiment, the olefinic monomer is a straight-chain, .alpha.-olefinic monomer containing from 8 to 12 carbon atoms, the alcohol alkoxylate is 2-ethoxyethanol, the ketone is methyl ethyl ketone, and the oligomer product has a kinematic viscosity at 100.degree. C. of less than 1.7 cSt. Before removal of unreacted monomer, the oligomer product is at least 50 wt. % dimer, at least 80 wt. % dimer plus trimer, and less than 3.25 wt. % tetramer and greater.

REFERENCES:
patent: 4436947 (1984-03-01), Morganson et al.
patent: 5068487 (1991-11-01), Theriot
patent: 5095172 (1992-03-01), Lanier et al.
patent: 5420373 (1995-05-01), Hope et al.

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