In situ remedial alternative and aquifer properties...

Chemistry: analytical and immunological testing – Geochemical – geological – or geothermal exploration – In situ testing

Reexamination Certificate

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Details

C422S050000, C422S051000, C422S051000, C422S068100, C422S091000

Reexamination Certificate

active

07659123

ABSTRACT:
In general, the purpose of the probe system is to provide improved rapid field methods using re-designed direct push technology (DPT) and “push-pull testing” concepts to evaluate in situ chemical, biochemical, surfactant, adsorptive media, and leaching and fixation remediation technologies for hazardous subsurface contaminant(s). The probe system and methods described here when applied to a hazardous waste site being considered for in situ remediation of contaminants (organic or inorganic) by the listed treatment technologies will yield information that greatly reduces the uncertainty with regards to treatment effectiveness for the in situ soil, groundwater, and contaminant(s) conditions affecting dosage requirements and reaction rate(s) for various reactants. The probe system described here is multi-purpose in that it was designed: 1) to measure the relative permeability of the subsurface soil and groundwater to a liquid or gas ejectant, 2) to recover soil gas, soil, or groundwater samples for contaminant analyses, 3) to measure the chemical dosage and reaction, dissolution, adsorption, desorption, leaching, or fixation rate of a reactant such as a chemical or biochemical oxidant, metallic or bimetallic dehalogenating agent, surfactant or emulsifier solution, adsorbent media regenerant, leaching or fixation reagent that is injected into the matrix and withdrawn during a push-pull test, 4) to perform combinations of the above, 5) to measure the in situ adsorption capacity of adsorbent media and subsequently measure the effectiveness of regenerant(s) for the adsorbent media, and (6) to measure the effectiveness of a treated soil column for inorganic contaminant(s) leaching or fixation. In addition to being an in situ remedial alternatives evaluation tool, the probe system can be used as a reactant(s) delivery device after the specific remedial technology has been selected.

REFERENCES:
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Haggerty, R., et al., “Simplified Method of “Push-Pull” Test Data Analysis for Determining In Situ Reaction Rate Coefficients”, Reprinted from Ground Water, vol. 36, No, 2, Mar.-Apr. 1998, 314-324.
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Istok, J.D., et al., “Laboratory and Field Investigation of Surfactant Sorption Using Single-Well, Push-Pull Tests”, Department of Civil Engineering, Oregon State University, vol. 37, No. 4, Ground Water, Jul.-Aug. 1999, 589-598.
Istok, J.D., et al., “Single-Well “Push-Pull” Partitioning Tracer Test for NAPL Detection in the Subsurface”, Environmental Science & Technology, vol. 36, No. 12, 2002, 2708-2716.
Schroth, M.H., et al., “In Situ Evaluation of Solute Retardation Using Single-Well Push-Pull Tests”, 2000 Elsevier Science Ltd., 13 pages.
Schroth, M.H., et al., “In Situ Assesment of Microbial Sulfate Reduction in a Petroleum-Contaminated Aquifer Using Push-Pull Tests and Stable Sulfur Isotope Analyses”, 2001 Elsevier Science B.V., 17 pages.
Snodgrass, M., et al., “A Method to Infer In Situ Reaction Rates From Push-Pull Experiments”, vol. 36, No. 4, Ground Water, Jul.-Aug. 1998, 645-650.

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