Electrolysis: processes – compositions used therein – and methods – Electrolytic analysis or testing – For corrosion
Patent
1997-05-08
1999-03-30
Tung, T.
Electrolysis: processes, compositions used therein, and methods
Electrolytic analysis or testing
For corrosion
204404, 205777, G01N 2726
Patent
active
058883746
ABSTRACT:
A method and apparatus are provided for monitoring localized pitting corrosion in metal pipes or storage vessels. Electrochemical probes are used for sensing electrochemical noise voltage values and electrochemical noise current values. The root-mean-square electrochemical noise current and voltage values are calculated and stored for the sensed electrochemical noise voltage values and the electrochemical noise current values. The stored electrochemical noise current and voltage values are processed by transforming the stored electrochemical noise current and voltage values into power spectral density data utilizing a fast Fourier transform. A slope of the power spectral density data relative to frequency is calculated. The electrochemical probes include a pair of working electrodes formed of the same material of the monitored metal pipes or storage vessels and a reference electrode formed of a corrosion resistant material. A linear slope of a low-frequency portion of the power spectral density data is calculated by using a least-square method.
REFERENCES:
patent: 4575678 (1986-03-01), Hladky
patent: 5139627 (1992-08-01), Eden et al.
patent: 5151163 (1992-09-01), Miller
Frank James R.
Lin YuPo J.
Pope Daniel H.
St. Martin Edward J.
The University of Chicago
Tung T.
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