In situ modification of gelatin carboxyl groups

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430539, 430621, 430640, 530354, G03C 1005, G03C 1494, G03C 130, G03C 176

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active

053914775

ABSTRACT:
A photographic element comprising a modified gelatin whereby the modification results in carbamoyl groups by forming peptide bonds using fast-acting hardener. The derivatization involves initial reaction with a carboxyl activator followed by addition of a substituted amine thereby forming an amide linkage on the polypeptide chain. The resulting gelatin and photographic elements comprising such gelatin have a decreased propensity for water absorption without the loss of sensitometric properties.

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T886,014 Defensive Publication Published May 11, 1971 886 OG 215 Gelatin With Improved Chemical Setting Properties.
Derwent Abstract, Nitta Gelatin Inc., Improved Alkali-Treated Gelatin and Preparation Thereof, JP2305876, Abstract, Dec. 19, 1990.
T. D. Weatherill, R. W. Henning and K. A. Smith, Solid State Structural Characterization of Gelatin Crosslinked with a Variety of Hardeners, Journal of Photographic Science, Nos. 5/6, Bath, GB, 40 (1992), 220-221, Sep. 15-20, 1991.

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