Mineral oils: processes and products – Chemical conversion of hydrocarbons – With prevention or removal of deleterious carbon...
Patent
1996-04-18
1997-11-25
Myers, Helane
Mineral oils: processes and products
Chemical conversion of hydrocarbons
With prevention or removal of deleterious carbon...
208 83, 208 91, 585820, 585823, 585824, 585450, C10G 916
Patent
active
056908091
ABSTRACT:
An improved process is provided for in situ mitigation of coke buildup and porous catalyst used for the processing of hydrocarbon feed stocks. The process exhibits improved catalyst activity over extended periods and the process comprises the pretreatment of hydrocarbon feed stocks to reduce impurities in the feed stocks in the form of peroxides and oxygen compounds that promote the formation of coke precursors, which precursors are typically in the form of olefinic oligomers. The process includes contacting the pretreated feed stream with a suitable catalyst under sub-critical, near-critical and supercritical conditions.
REFERENCES:
patent: 4176045 (1979-11-01), Leftin et al.
patent: 4243831 (1981-01-01), Malloy et al.
patent: 5030788 (1991-07-01), Amelse et al.
patent: 5221462 (1993-06-01), Reid et al.
Titscher, Melmut et al.; "A Mild and Effective Method for the Reactivation or Maintenance of the activity of Heterogeneous Catalysts", Angew. Chem. Int. Ed. Engl., 20, (1981), No. 10, pp. 892-894.
Tiltscher, H. et al.; "Trends in High Pressure Chemical Reaction Engineering"; Chem. Eng. Sci. , vol. 42, No. 5, pp. 959-977, 1987.
Saim, Said et al.; "Isomerization of 1-Hexene on Pt/.gamma.-Al.sub.2 O.sub.3 Catalyst at Subcritical and Supercritical Reaction Conditions: Pressure and Temperature Effects on Catalyst Activity"; The Journal of Supercritical Fluids, vol. 3, No. 4, pp. 214-221, 1990.
Saim, Said et al.; "Phase and Reaction Equilibria Considerations in the Evaluation and Operation of Supercritical Fluid Reaction Processes"; Supercritical Fluid Science and Technology ; Johnston, K.P. et al.,Eds., ACS Symposium Series No. 406, pp. 301-316 (1989).
Manos, Georgios et al.; "Coke Removal from a Zeolite Catalyst by Supercritical Fluids", Chem. Eng. Technol., 14 (1991) 73-78.
Saim, Said et al.; "Isomerization of 1-Hexene over Pt/.gamma.-Al.sub.2 O.sub.3 Catalyst: Reaction Mixture Density and Temperature Effects on Catalyst Effectiveness Factor, Coke Laydown, and Catalyst Micromeritics", Journal of Catalysis, 131, 445-456 (1991).
Baptist-Nguyen, Sarah et al.; "Coking and Activity of Porous Catalysts in Supercritical Reaction Media"; AIchE Journal, vol. 38, No. 7, pp. 1027-1037, Jul. 1992.
Tiltscher, et al.; "Utilization of SupercriticalFluid Solvent-Effects in Heterogeneous Catalysis"; Ber. Bunsenges. Phys. Chem., 88, (1984), pp. 897-900.
Clark Michael C.
Saim Said
Subramaniam Bala
Center For Research, Inc.
Myers Helane
LandOfFree
In situ mitigation of coke buildup in porous catalysts by pretre does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with In situ mitigation of coke buildup in porous catalysts by pretre, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and In situ mitigation of coke buildup in porous catalysts by pretre will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2103650