Impact resistance polymer blends of crystalline...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C525S240000

Reexamination Certificate

active

11359091

ABSTRACT:
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i)13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tmethat remains essentially the same and a Tmaxthat decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.

REFERENCES:
patent: 4542199 (1985-09-01), Kaminsky et al.
patent: 4544762 (1985-10-01), Kaminsky et al.
patent: 4874880 (1989-10-01), Miya et al.
patent: 4960878 (1990-10-01), Crapo et al.
patent: 5015749 (1991-05-01), Schmidt et al.
patent: 5041583 (1991-08-01), Sangokoya
patent: 5041584 (1991-08-01), Crapo et al.
patent: 5041585 (1991-08-01), Deavenport et al.
patent: 5044438 (1991-09-01), Young
patent: 5057475 (1991-10-01), Canich et al.
patent: 5064802 (1991-11-01), Stevens et al.
patent: 5093415 (1992-03-01), Brady, III et al.
patent: 5096867 (1992-03-01), Canich
patent: 5134209 (1992-07-01), Job et al.
patent: 5153157 (1992-10-01), Hlatky et al.
patent: 5198401 (1993-03-01), Turner et al.
patent: 5218071 (1993-06-01), Tsutsui et al.
patent: 5272236 (1993-12-01), Lai et al.
patent: 5278272 (1994-01-01), Lai et al.
patent: 5296433 (1994-03-01), Siedle et al.
patent: 5324800 (1994-06-01), Welborn, Jr. et al.
patent: 5350723 (1994-09-01), Neithamer et al.
patent: 5408017 (1995-04-01), Turner et al.
patent: 5427991 (1995-06-01), Turner
patent: 5504049 (1996-04-01), Crowther et al.
patent: 5504172 (1996-04-01), Imuta et al.
patent: 5556928 (1996-09-01), Devore et al.
patent: 5599761 (1997-02-01), Turner
patent: 5616664 (1997-04-01), Timmers et al.
patent: 5621127 (1997-04-01), Langhauser et al.
patent: 5625087 (1997-04-01), Devore et al.
patent: 5703257 (1997-12-01), Rosen et al.
patent: 5710224 (1998-01-01), Alt et al.
patent: 5721185 (1998-02-01), LaPointe et al.
patent: 5728855 (1998-03-01), Smith et al.
patent: 5731253 (1998-03-01), Sangokoya
patent: 5767208 (1998-06-01), Turner et al.
patent: 5840389 (1998-11-01), Asanuma et al.
patent: 5874505 (1999-02-01), Saito et al.
patent: 5883204 (1999-03-01), Spencer et al.
patent: 5907021 (1999-05-01), Turner et al.
patent: 5919983 (1999-07-01), Rosen et al.
patent: 5962714 (1999-10-01), McCullough et al.
patent: 5965677 (1999-10-01), Stephan et al.
patent: 5965756 (1999-10-01), McAdon et al.
patent: 5972822 (1999-10-01), Timmers et al.
patent: 5998039 (1999-12-01), Tanizaki et al.
patent: 6013819 (2000-01-01), Stevens et al.
patent: 6015868 (2000-01-01), Nickias et al.
patent: 6034240 (2000-03-01), La Pointe
patent: 6043363 (2000-03-01), LaPointe et al.
patent: 6074977 (2000-06-01), Rosen et al.
patent: 6103657 (2000-08-01), Murray
patent: 6150297 (2000-11-01), Campbell, Jr. et al.
patent: 6197886 (2001-03-01), Chatterjee et al.
patent: 6207756 (2001-03-01), Datta et al.
patent: 6245856 (2001-06-01), Kaufman et al.
patent: 6248829 (2001-06-01), Fischer et al.
patent: 6268438 (2001-07-01), Ellul et al.
patent: 6268444 (2001-07-01), Klosin et al.
patent: 6288171 (2001-09-01), Finerman et al.
patent: 6303719 (2001-10-01), Murray et al.
patent: 6326433 (2001-12-01), Wang et al.
patent: 6342565 (2002-01-01), Cheng et al.
patent: 6372847 (2002-04-01), Wouters
patent: 6444302 (2002-09-01), Srinivas et al.
patent: 6500563 (2002-12-01), Datta et al.
patent: 6515155 (2003-02-01), Klosin et al.
patent: 6525157 (2003-02-01), Cozewith et al.
patent: 6635715 (2003-10-01), Cozewith et al.
patent: 6642316 (2003-11-01), Datta et al.
patent: 6747114 (2004-06-01), Karandinos et al.
patent: 6750284 (2004-06-01), Dharmarajan et al.
patent: 6943215 (2005-09-01), Stevens et al.
patent: 7109269 (2006-09-01), Stevens et al.
patent: 2002/0062011 (2002-05-01), Campbell, Jr. et al.
patent: 2002/0165329 (2002-11-01), Klosin et al.
patent: 2003/0004286 (2003-01-01), Klosin et al.
patent: 2003/0130430 (2003-07-01), Cozewith et al.
patent: 2004/0116609 (2004-06-01), Datta et al.
patent: 0 277 003 (1988-08-01), None
patent: 0 468 537 (1992-01-01), None
patent: 0 468 651 (1992-01-01), None
patent: 0 844 280 (1998-05-01), None
patent: 0 949 278 (1999-10-01), None
patent: 0 949 279 (1999-10-01), None
patent: 0 949 278 (2000-09-01), None
patent: 0 949 279 (2000-09-01), None
patent: 1 063 244 (2000-12-01), None
patent: 88/05792 (1988-08-01), None
patent: 88/05793 (1988-08-01), None
patent: 90/07526 (1990-07-01), None
patent: 93/21238 (1993-10-01), None
patent: 93/21238 (1993-10-01), None
patent: 93/21242 (1993-10-01), None
patent: 93/25590 (1993-12-01), None
patent: 94/00500 (1994-01-01), None
patent: 94/03506 (1994-02-01), None
patent: 96/00244 (1996-01-01), None
patent: 96/13530 (1996-05-01), None
patent: 96/23010 (1996-08-01), None
patent: 97/22635 (1997-06-01), None
patent: 97/42241 (1997-11-01), None
patent: 98/41529 (1998-09-01), None
patent: 98/50392 (1998-11-01), None
patent: 99/14250 (1999-03-01), None
patent: 00/01745 (2000-01-01), None
patent: 02/051634 (2002-07-01), None
patent: 02/51928 (2002-07-01), None
patent: 2004/035681 (2004-04-01), None
patent: 2004/060994 (2004-07-01), None
patent: 2004/063270 (2004-07-01), None
Alt, Helmut G., et al.,Chem. Rev. 2000, 100, 1205-1221.
Brintzinger, Huns H., et al.,Angew. Chem. Int. Ed. Engl., 1995, 34, 1143-1170.
Chen, Eugene You-Xian, et al.,Chem. Rev.2000, 100, 1391-1434.
Coates, Geoffrey W.,Chem. Rev.2000, 100, 1223-1252.
Hazlitt, Lonnie G.,Journal of Applied Polymer Science: Applied Power Symposium45, 25-37 (1990).
Herzog, Timothy A., et al.,J. Am. Chem. Soc.1996, 118, 11988-11989.
Ittel, Steven D., et al.,Chem. Rev.2000, 100, 1169-1203.
Lambert, Joseph B., et al.,J. Chem. Soc., Chem. Commun., 1993, 383-384.
Mathur, Naresh C., et al.,Tetrahedron, vol. 41, No. 8, 1509-1516, 1985.
Otocka, E.P., et al.,Macromolecules, vol. 4, No. 4, Jul.-Aug. 1971, 507-514.
Randall, James C.,JMS-Rev. Macromol. Chem. Phys., C29(2 & 3), 201-317, 1989.
Resconi, Luigi, et al.,Chem., Rev.2000, 200, 1253-1345.
Scholte, Th. G., et al..Journal of Applied Polymer Sciencevol. 29, 3763-3782, 1984.
Scollard, John D., et al.,J. Am. Chem. Soc.1996, 118, 10008-10009.
Veghini, Dario, et al.,J. Am. Chem. Soc.1999, 121, 564-573.
Wang, Chumming, et al.,Organometallics, vol. 17, No. 15, 1998, 3149-3151.
Wild, L. et al.,Journal of Polymer Science Polymer Physics Edition, vol. 20, 1982, 441-455.
Younkin, Todd R., et al.,Science, vol. 287, Issue 5452, 2000, 460-462.
News Release, Japan Polychem Launches WINTEC Metallocene-Based PP Random Copolymer, Oct. 25, 2001, http://www.m-kagaku.co.jp/english/rel/2001/102501.htm.
Product Sample Report for Escorene PP 4292, Polymer Science Laboratory of the Baytown Polymer Center, Exxon Chemical, May 9, 2000.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Impact resistance polymer blends of crystalline... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Impact resistance polymer blends of crystalline..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Impact resistance polymer blends of crystalline... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3806406

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.