Immobilization of organic species on refractory inorganic oxides

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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55386, 210656, 252184, 502 7, 502150, 502155, 502158, 502162, 502224, 502227, 502401, B01J 2022, B01J 3138, B01J 3136, B01D 1508

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045201226

ABSTRACT:
A broad variety of modified inorganic oxides may be prepared by surface-metallating the oxide with a metal tetrahalide followed by displacement of a halogen bonded to the metal by a nucleophilic organic functional group. The results are organic moieties coating the surface of the oxide by being covalently bonded to a metal which, in turn, is covalently bonded to an oxygen originally associated with a surface hydroxyl of the inorganic oxide.

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patent: 4199330 (1980-04-01), Nestrick et al.
patent: 4333847 (1982-06-01), Tran et al.
patent: 4377555 (1983-03-01), Hancock et al.
patent: 4416992 (1983-11-01), Arena et al.

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