Imino-amide catalyst compositions for the polymerization of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C556S020000, C556S028000, C556S032000, C556S042000, C556S045000, C556S051000, C556S057000, C556S001000, C556S117000, C556S136000, C556S146000

Reexamination Certificate

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06919467

ABSTRACT:
The present invention provides a catalyst precursor and catalyst system comprising the precursor, an embodiment of the precursor is selected from the following structures:wherein T is a bridging group; M is selected from Groups 3 to 7 atoms, and the Lanthanide series of atoms the Periodic Table of the Elements; Z is a coordination ligand; each L is a monovalent, bivalent, or trivalent anionic ligand; X and Y are each independently selected from nitrogen, oxygen, sulfur, and phosphorus; R is a non-bulky substituent that has relatively low steric hindrance with respect to X; and R′ is a bulky substituent that is sterically hindering with respect to Y.

REFERENCES:
Cotton, Frank Albert and Wilkinson, Geoffrey,Advanced Inorganic Chemistry A Comprehensive Text, John Wiley & Sons, 776-778, 790, 792-793 (1980).

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