Stock material or miscellaneous articles – Composite
Patent
1996-01-26
1998-07-21
Zimmerman, John J.
Stock material or miscellaneous articles
Composite
327524, 427331, 540145, 514185, C07B 4700, C07D48722, H03G 100, A01N 5502
Patent
active
057833060
ABSTRACT:
Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core.
REFERENCES:
patent: 5171741 (1992-12-01), Dougherty
patent: 5371199 (1994-12-01), Therien et al.
patent: 5493017 (1996-02-01), Therien et al.
patent: 5599924 (1997-02-01), Therien et al.
Boyle et al., "Iodination and Hek Alkynylation . . . " in J. Chem. Soc., Chem. Commun., p. 527, no month, 1995.
Imahori et al., "Synthesis and Properties . . . " in Bull. Chem. Soc. Jpn. 67, 2500, p. 2500, Sep. 1994.
Imahori et al., "Polyphytine-Quinone . . . " in Chem. Letters, pp. 1215-1218, no month, 1993.
DiMagno et al., "Catalytic Conversion . . . " in J. Am. Chem. Soc. 115, p. 2513, no month, 1993.
Anderson, "Meso-Alkynyl Porphyrins" in Tetrahedron Letts. vol. 33, p. 1101, no month, 1992.
Blanchard-Desce and Lehn, "Chain-length dependence of the quadratic hyperpolarizability of push-pull polyenes and carotenoids. Effect of end groups and conjugation path", Chem. Phys., 1994, (no month) 181, 281-289.
Burland, et al., "Second-Order Nonlinearity in Poled-Polymer Systems", Chem. Rev., (no month) 1994, 94, 31-75.
Cadiot and Chodkiwicz, "Couplings of Acetylenes", Chapter 9, pp. 597-647, Marcel Dekker, 1964 (no month).
Clays, et al., "Hyper-Rayleigh Scattering in Solution", Phys. Rev. Lett., (Jun.) 1991, 66, 2980-2983.
Clays, et al., "Nonlinear Optical Properties of Proteins Measured by Hyper-Rayleigh Scattering in Solution", Science, (Nov.) 1993, 262, 1419-1422.
Dehu, et al., "Donor-Acceptor Diphenylacetylenes: Geometric Structure, Electronic Structure, and Second-Order Nonlinear Optical Properties", J. Am. Chem. Soc., (no month) 1993, 115, 6198-6206.
Dhenaut, et al., "Chiral metal complexes with large octupolar optical nonlinearities", Nature, (Mar.) 1995, 374, 339-342.
DiMagno, et al., "Catalytic Conversion of Simple Haloporphyrins into Alkyl-, Pyridyl-, and Vinyl-Substituted Porphyrins", Am. Chem. Soc., (no month) 1993, 115, 2513-2515.
DiMagno, et al, "Facile Synthesis of meso-Tetrakis(perfluoroalkyl) porphyrins: Spectroscopic Properties and X-ray Crystal Structure of Highly Electron-Deficient 5,10,15,20-tetrakis (heptafluoropropyl) porphyrin", J. Org. Chem., (no month) 1994, 59, 6943-6948.
DiMagno, et al., "Facile Elaboration of Polphyrins via Metal-Mediated Cross-Coupling", J. Org. Chem., (no month) 1994, 59, 5983-5993.
Eglinton and McCrae, "The Coupling of Acetylenic Compounds", Adv. Org. Chem., (no month) 1963, 4, 225-277.
Gilmour, et al., "Synthesis of Diarylthiobarbituric Acid Chromophores with Enhanced Second-Order Optical Nonlinearities and Thermal Stability", Chem. Mater, (no month), 1994, 6, 1603-1604.
Laidlaw, et al., "Large second-order optical polarizabilities in mixed-valency metal complexes", Nature, (May) 1993, 363, 58-60.
Lin, et al., "Highly Conjugated, Acetylenyl Bridged Porphyrins: New Models for Light-Harvesting Antenna Systems", Science, (May) 1994, 264, 1105-1111.
Marder, et al., "Large First Hyperpolarizabilities in Push-Pull Polyenes by Tuning of the Bond Length Alternation and Aromaticity", Science, (Jan.) 1994, 263, 511-514.
Patai, et al., The Chemistry of Functional Groups, Supplement C, Part 1, pp. 529-534, Wiley, 1983 (no month).
Pauley and Wang, "Hyper-Rayleigh scattering studies of first order hyperpolarizability of tricyanovinylthiophene derivatives in solution", J. Chem. Phys., (Apr.) 1995, 102, 6400-6405.
Peng, et al., "Large Photorefractivity in an Exceptionally Thermostable Multifunctional Polyamide", J. Am. Chem. Soc., (no month) 1994, 116, 6003-6004.
Rao, et al., "Dramatically Enhanced Second-order Nonlinear Optical Susceptibilities in Tricyanovinylthiophene Derivatives", J. Chem. Soc. Chem. Commun., (no month) 1993, 1118-1119.
Scamporrino, "Main-Chain Porphyrin Polymers. 1. Synthesis and Characterization of Polyethers Containing Porphyrin Units and Their Metal Derivatives", Macromolecules, (Mar.) 1992, 25, 1625-1632.
Sessler, et al., "A Expanded Porphyrin: The Synthesis and Structure of a New Aromatic Pentadentate Ligand", J. Am. Chem. Soc., (no month) 1988, 110, 5586-5588.
Sessler, et al., "Sapphyrins and Heterosapphyrins", Tetrahedron, (no month) 1992, 48, 9661-9672.
Sessler, et al., "Synthesis and Characterization of Diaryl Sapphyrins Prepared under Lindsey-Type Conditions", J. Org. Chem., (no month) 1995, 60, 5975-5978.
Sessler, et al., "Synthesis and Structural Studies of Sapphyrin a 22-.pi.-Electron Pentapyrrolic Expanded Porphyrin", J. Am. Chem. Soc., (no month) 1990, 112, 2810-2813.
Stiegman, et al., "The Electronic Structure and Second-Order Nonlinear Optical Properties of Donor-Acceptor Acetylenes: A Detailed Investigation of Structure-Property Relationships", J. Am. Chem. Soc., (no month) 1991, 113, 4658-7666.
Terhune, et al., "Measurements of Nonlinear Light Scattering", Phys. Rev. Lett., (Apr.) 1965, 14, 6861-684.
Imahori, et al., "Porphyrin-Quinone Compounds with a Spacer of Diacetylene Unit", Chemistry Leeters, (no month) 1993, 1215-1218.
Suslick, et al., "Push-Pull Porphyrins as Nonlinear Optical Materials", J. Am. Chem. Soc., (no month) 1992, 114, 6928-6930.
LeCours, et al., "Push-Pull Arylethynyl Porphyrins: New Chromophores That Exhibit Large Molecular First-Order Hyperpolarizabilities", J. Am. Chem. Soc., (no month) 1995, 118, Issue 3, pp. A-H.
DiMagno Stephen G.
Therien Michael J.
LaVilla Michael
Trustees of the University of Pennsylvania
Zimmerman John J.
LandOfFree
Hyperpolarizable compounds and devices fabricated therefrom does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Hyperpolarizable compounds and devices fabricated therefrom, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hyperpolarizable compounds and devices fabricated therefrom will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1645064