Hydroxyfluoroalkyl-substituted styrenes and polymeric compositio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 92, 525176, 525178, C08L 2712

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active

052410072

ABSTRACT:
Fluorinated styrenes of the formula I; ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl and R.sub.2 is the repeating unit ##STR2## where x is zero or any positive integer, which are useful as compatibilizing and toughening agents for various polymers such as styrene, dienes (butadiene, isoprene, etc.) acrylates, polymethacrylates, polycarbonates, polyesters, polyamides, etc. Particularly preferred are p-(1,1,1,3,3,3-hexafluoro-2-hydroxy isopropyl)-.alpha.-methylstyrene, polymers thereof, block and random copolymers thereof and polymer blends incorporating the same.

REFERENCES:
patent: 3179640 (1965-04-01), Middleton
patent: 4640965 (1987-02-01), Falcetta et al.
patent: 4690993 (1987-09-01), Falcetta et al.
Macromolecules, vol. 24, No. 2, Jan. 21, 1991, A.C.S. "Spinodal Decomposin in a Hydrogen-Bonded Polymer Blend", pp. 464-473.
Journal of Macromolecular Science-Chemistry, A21, pp. 1181-1216 (1954), Pearce, et al., "Polymer Compatibilization Through Hydrogen Bonding".

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