Hydroxy methyl carbazole acetic acid and esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D20982

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active

041500318

ABSTRACT:
A process for the preparation of 6-chloro-.alpha.-methylcarbazole-2-acetic acid from 6-chloro-.alpha.-hydroxy-.alpha.-methylcarbazole-2-acetic acid and/or 6-chloro-.alpha.-methylene-2-carboxylic acid, is described. The preparation of intermediates, such as, 6-chloro-.alpha.-hydroxy-.alpha.-methylcarbazole-2-acetic acid and lower alkyl carbazole-2-oxalate, inter alia, is also described.

REFERENCES:
patent: 3896145 (1975-07-01), Berger et al.
patent: 4057640 (1977-11-01), Biere et al.
Gore "Friedel-Crafts and Related Reactions", vol. III, pt. 1, pp. 94-95 (1964).
Sumpter et al., "The Chemistry of Heterocyclic Compounds", vol. 8, pp. 70-109 (1954).
Clemence et al., "J. Med. Chem.", vol. 9, p. 390 (1974).

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