Hydroxy aromatic compounds from alkali metal hydroxide and monon

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568780, C07C 3902

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active

045337632

ABSTRACT:
This invention pertains to a process for preparing hydroxy mononuclear aromatic compounds by reacting an alkali metal hydroxide with a mononuclear aromatic compound, e.g., benzene, xylene or toluene. The reaction is carried out in the presence of a metallic hydrogenation catalyst, suitably copper, nickel, rhodium or cobalt, the metal being present in an amount sufficient for catalyzing the reaction. The hydroxy mononuclear aromatic compound is then formed by adding a protonating agent to the resulting reaction product, with the protonating agent liberating the hydroxy compound from the salt.

REFERENCES:
patent: 2119213 (1938-05-01), Kasehagen et al.
patent: 2736752 (1956-02-01), Hoffman et al.
patent: 3230266 (1983-12-01), Baldwin et al.
patent: 3520940 (1970-07-01), Smith
patent: 4172960 (1979-10-01), Baldwin et al.

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