Hydroxidation of gaseous olefins with ethylbenzene hydroperoxide

Details Hydroxidation of gaseous olefins with ethylbenzene hydroperoxide Hydroxidation of gaseous olefins with ethylbenzene hydroperoxide

1978-12-18

1980-05-20

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568815, 568860, C07C 2716, C07C 2902, C07C 3116, C07C 4978

Patent

active

042039266

ABSTRACT:
Ethylbenzene hydroperoxide and ethylene or propylene are converted to acetophenone, 1-phenylethanol and the corresponding glycol at high selectivity in a process in which ethylbenzene hydroperoxide is reacted with the olefin in a two-phase liquid, organic-aqueous reaction system in the presence of osmium tetroxide and cesium, rubidium or potassium hydroxide.

REFERENCES:
patent: 3488394 (1970-01-01), Cummins
patent: 3665047 (1972-05-01), Gislon et al.
patent: 3860662 (1975-01-01), Kollar

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