Hydroxamic acid derivatives

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

Reexamination Certificate

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Details

C546S207000

Reexamination Certificate

active

07015234

ABSTRACT:
Compounds of the general formula (I)are described wherein R1and R2, which may be the same or different, is each a hydrogen atom or a CF3, CF2H or CFH2group, provided that when one of R1and R2is a hydrogen atom, then the other is a CF3, CF2H or CFH2group, and the salts, solvates or hydrates thereof. Compounds of the invention are potent MMP inhibitors which advantageously do not cause tendonitis in a relevant animal model. Compounds of the invention may be expected to be of use in medicine, especially where the avoidance of side effects, such as joint pain, is desired.

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Copy of the PCT International Search Report dated Oct. 24, 2002 (PCT/GB02/03656.
Barta, T.E., et al., “Synthesis and activity of selective MMP inhibitors with an aryl backbone,”Bioorganic&Medicinal Chem. Letts.,2000, 10, 2815-2817.
Barta, T.E., “Selective, orally active MMP inhibitors with an aryl backbone,”Bioorganic&Medicinal Chem. Letts.,2001, 11, 2481-2483.
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Solorzano, C.C., et al., “Involvement of 26-kDa cell-associated TNF-α in experimental hepatitis and exacerbation of liver injury with a matrix metalloproteinase inhibitor,”J. of Immunol.,1997, 158, 414-419.

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