Hydrosol droplet casting process for production of nuclear fuel

Plastic and nonmetallic article shaping or treating: processes – Shaping or treating radioactive material

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2523011S, 423252, G21C 2100

Patent

active

041939530

ABSTRACT:
A hydrosol containing, in nitrate form, a fuel or fuel-and-breeder material which is projected horizontally in the form of droplets into a gas phase containing gaseous ammonia and allowed to fall in a drip-casting column into a precipitation bath containing ammonium hydroxide. In the gas phase, the droplets are hardened just enough to prevent their deformation upon penetrating into the precipitation bath where the hardening is completed. A falling height of 5 cm is suitable. The granules are washed free of ammonium nitrate, then dried, and then sintered. The heavy metal content in the hydrosol is between 1.5 and 3 moles per liter, and the pH value of the precipitation bath is between 8 and 9. The hydrosol contains the heavy metal in oxide form and the process can be used with a thorium oxide hydrosol or a hydrosol that, in addition to thorium oxide, contains the oxide of hexavalent uranium, in the latter case the hexavalent uranium being present in a proportion up to 25% by weight of the total heavy metal. The process is also applicable to producing kernels of mixed thorium and plutonium oxides. In the case of uranium-containing granules, the sintering step is carried out in a reducing atmosphere to convert the uranium to the tetravalent state.

REFERENCES:
patent: 3345437 (1967-10-01), Flack et al.
patent: 3586742 (1971-06-01), Chin et al.
patent: 4060497 (1977-11-01), Huschka et al.
Brambilla et al., Energia Nucleare, vol. 17, No. 4, Apr. 1, 1970, pp. 217 224.
Vygen et al., Kerntechnik, vol. 12, No. 4, 1970, pp. 159 to 164.

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