Hydrosilation process using a (.eta..sup.5 -cyclopentadienyl)tri

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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427 541, 428345, 428447, 502152, 528 15, 528 31, 556 11, 556474, 522 66, 522 99, 522148, B01J 1912

Patent

active

046004840

ABSTRACT:
A process for the addition of compounds containing silicon-bonded hydrogen to compounds containing aliphatic unsaturation. The process is activated by actinic radiation and is conducted in the presence of a platinum complex having one cyclopentadienyl group that is eta-bonded to the platinum atom and three aliphatic groups that are sigma-bonded to the platinum atom.

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Robert A. Faltynek, "Transition-Metal Photocatalysis: Rhodium(i)-Promoted Hydrosilation Reactions", Inorg. Chem. 1981, 20(5), pp. 1357-1362.
S. D. Robinson and B. L. Shaw, J. Chem. Soc. 1965, 1529.

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