Coating processes – With post-treatment of coating or coating material – Chemical agent applied to treat coating
Patent
1995-05-17
1997-03-25
Beck, Shrive
Coating processes
With post-treatment of coating or coating material
Chemical agent applied to treat coating
427354, 427387, 4273882, 4273897, 4273935, 4274072, 427409, 4274121, B05D 310
Patent
active
056142633
ABSTRACT:
A chemically adsorbed film containing hydrophilic groups is formed on a substrate such that it is chemically bonded by Si covalent bonds to the substrate. The adsorbed film has an improved hydrophilic property. In addition,the film provides an excellently durable and transparent fog-proof substrate. According to the method of the invention, a substrate containing hydrophilic groups is contacted with a non-aqueous solution containing a surface active material having straight chain molecules each having at one end a chlorosilyl group and at the other end at least one functional group selected from the group consisting of a bromo group, iodo group, cyano group, thiocyano group, chlorosilyl group etc. to cause a dehydrochlorination reaction between hydrophilic groups on the substrate surface and chlorosilyl groups of the surface active material, thereby forming a chemically adsorbed film on the substrate surface. The functional group at the other end of the surface active material is converted into at least one hydrophilic group selected from the group consisting of --OH, --COOH, --NH.sub.2, .dbd.NH, --N.sup.+ R.sub.3 X.sup.- (X representing a halogen atom, R represents a loner alkyl group), --NO.sub.2, --SH, and --SO.sub.3 H groups.
REFERENCES:
patent: 3781251 (1973-12-01), Hermes
patent: 4539061 (1985-09-01), Sagiv
patent: 4847160 (1989-07-01), Munz et al.
patent: 4992300 (1991-02-01), Ogawa et al.
Mino Norihisa
Ogawa Kazufumi
Soga Mamoru
Beck Shrive
Cameron Erma
Matsushita Electric - Industrial Co., Ltd.
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