Hydrophobic, oleophobic and alcohol-resistant fluorochemical...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C524S507000, C508S465000, C508S478000

Reexamination Certificate

active

10887451

ABSTRACT:
A fluorochemical additive is the reaction product under polymerization conditions of monomers that include: (a) an aromatic polycarboxylic acid as an anhydride, ester, or ester chloride; (b) at least one fluorinated reactant; and (c) at least one aliphatic amine, mercaptan, or alcohol. Optionally, a crosslinking agent can be used. The components of the additive all can be viewed as contributing to the performance of the disclosed additive. The fluorine-containing component is generally insoluble in molten polymers and will tend to migrate to the cooled surface thereof where the fluorinated moieties provide repellency characteristics when used in adequate quantities, generally at least about 30 wt % depending on the fluorinated reactant used to make the additive. The aromatic component appears to facilitate solubility and speed up the orientation process of the additive within the molten polymer. The aliphatic component to the reaction mixture appears to assist in anchoring the reaction product additive in the bulk polymer structure. Together, the components form a fluorinated reaction product additive that can be added to a molten polymer for integration into the resulting product to impart improved resistance to oil, water, and alcohol.

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patent: 6413918 (2002-07-01), Beatty
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patent: 2004/0087709 (2004-05-01), Crater
patent: 2004/0097158 (2004-05-01), Rudisill
Zonyl BA Fluorotelomer MSDS, DuPont Chemical (Apr. 19, 2001).
Lange, Cleston C.; Biodegradation Screen Study for Telomer-Type Alcohols, Nov. 6, 2002.

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