Hydrophobic coating for ink jet printing heads

Details Hydrophobic coating for ink jet printing heads Hydrophobic coating for ink jet printing heads

1998-06-11

2001-09-04

Barlow, John (Department: 2853)

Incremental printing of symbolic information

Ink jet

Ejector mechanism

C347S020000, C347S067000

Reexamination Certificate

active

06283578

ABSTRACT:

The present invention concerns inkjet printheads with anti-wetting-coating. The term “anti-wetting”-coating signifies, vis-a-vis the ink, a hydrophobe coating, specifically a jet plate coating.
An essential pre-requisite for a clean print image of an inkjet operating-based printer is a symmetrical droplet form, i.e. there must be no unilateral influence upon the ink when exiting from the print head. Since inkjet print heads are customarily manufactured in sandwich-type construction and may consist of highly different materials, (silicon-wafer/channel-like structured polymer (PARAD)/Polyimide-Layer/alkaline earth glass) the print head, up to now, has usually been vaporized with a fluorine compound in order to produce a uniform anti-wetting-layer at the ink jet exits. The vaporization process is extremely costly and leads to unsatisfactory results. Furthermore, the face surface of the inkjet print head, which is rough as a result of sawing, must have been polished prior to vaporization, i.e. it must have been lapped, that is to say, smoothed out via costly and time-consuming process.
Specifically with respect to the circumstance that disposable print heads have in the meantime come on the market, which are each time exchanged together with the ink cartridge, the above described vaporization process, including its prerequisites, proves too expensive.
It is, therefore, the object of the invention to discover an anti-wetting-coating material which adheres well to the substrate material, and having hydrophobic properties with respect to the ink, which can be inexpensively applied and is cost-friendly.
Said object is solved by making available an Inkjet Print Head according to claim
1
and, in specifically beneficial fashion, according to the Sub-claims
2
to
7
.
Preference is given to the use of Compounds I as sole or principal component for the manufacture of the polymer material.
The anti-wetting-coating of the present invention is suitable for each type of jet exit surfaces (for example jet plate, with sandwich construction, side shooter, edge shooter, back shooter). It is, among others, chemically inert vis-a-vis the different ink systems, because it does not swell upon contact with ink. Depending upon the ink system to be employed, the wetting properties can readily be optimally adjusted or adapted by means of variation of the respective chemical groups.
The basic materials can be easily stored and are environmentally friendly.
By application of a material according to claim
1
as anti-wetting-layer, good adhesion is obtained with respect to the materials utilized for the heads; excellent compatibility with the thermal expansion of the layer-bonding has the result that the applied layers will not chip or flake off, even after being rejected to stress over a longer period of time. Wetting angles relative to water are achieved in the range of 80° to more than 90°, and in some cases up to more than 100°. Surprisingly, it was also discovered that with Inkjet Print Heads coated according to the invention, the roughness of the face surface due to wafer sawing is planarized. There also exists capability of pinhole-free application.
Specifically, via a process according to claim
12
, there is guarantee, in particularly beneficial manner, that the channels themselves are not pasted up with the coating.
Polymer materials as defined in claim
1
, belong to a material category of the so called ORMOCERS (ORganically MOdified CERamics). They may be ranked among the inorganic and organic polymers. Production takes place starting from alkoxides of silicon, and possibly, as supplement to other metals, which are totally or partially modified by organically polymerizable substituted groups. Via hydrolysis and condensation, the inorganic part of the network is formed, via polymerization, polyaddition or other organic coupling reactions the organic part (of reactive organic substituted groups).
The following systems have proven themselves as particularly suitable for use as polymer material for anti-wetting-coating.
TABLE 1
G-(Mol-%)
P(Mol-%)
2(Mol-%)
M(Mol-%)
T(Mol-%)
30-40
—
10-20
30-40
0-5
—
70-90
—
15-25
—
—
80-95
—
 5-15
—
—
65-75
—
20-40
—
—
35-45
25-35
20-40
—
—
50-70
25-35
 5-15
—
G = Glycidoxypropl-trimethoxysilane;
P = Phenyl-trimethoxysilane;
P2 = Diphenyl-silandiol;
M = Methacryl-oxypropyl-trimethoxysilane;
T = Tetra-ethoxy-silane.
The preferred manufacturing method for the material is that the desired silanes are first mixed with any other perhaps required additives (for example network builders or modifying substances), and, if required, under calefaction, hydrolyzed by addition of water. Addition of water can be done slowly, so that the system is initially supplied with sub-stoichiometrical quantities.
In one embodiment of the invention, the systems also contain one amino component, for example N-methyldiethanolamine (NMDA) and/or diethylenetriamine (DETA). This can act as an accelerator. The two aforementioned substances are preferably employed at a ratio of approximately 1:1 and in a volume of approximately 0.5-2, preferably approximately 1 volume-% relative to undiluted lacquer.
The liquid lacquer, produced as described above, is brought, where required, to a desired solid matter contents and can subsequently be applied as such on the print head or, as is preferred, in combination with a solvent (for example ethanol, acetone, propylacetate or similar). The preferred application procedure is spraying. Alternative possibilities are, for example, spin-coating, roll-application or tampon print. Additional possibilities are off-set print, application by brush or immersion application. The mode of application is usually selected in such manner that optimum adaptation is possible with respect to head geometry and head production sequence. After the application, the material is hardened (organically polymerized). This can be done for example via photo-chemical and/or thermal method, whereby, of course, for photo-chemical hardening photo-initiators need to be added to the lacquer, prior to application. In case of spray application, one can, for example, operate with a spray precompression of 0.5 to 2 bar, for example (jet cross sections: 0.1 to 0.3 mm). Spray distance can, for example, be 3 to 10 cm, specifically approximately 6 cm. In order to prevent any clogging of the fine inkjet exit apertures, Nitrogen can be passed through each print head, for example with a counter pre-compression of 0.5 bar.
Suitable photoinitiators are known to a person skilled in the art. For example, radically-ionic initiators can be employed such as Cyracure UVI 6974 by Union Carbide. Adding amines such as N-methyidiethanolamine and/or Diethylenetriamine shortly before application is particularly beneficial, even with utilization of radical photostarters such as for example Quantacure ITX (Rahn Chemie). The photo-initiators can, for example, be added in amounts of 1-5 mass-%, preferably approximately 2 mass-%, relative to the undiluted lacquer.
The solid matter contents of the lacquer produced in the initial phase is variable. For example, it can amount to between 30 to 80%. The adjustment is preferably made via rotary incorporation. Subsequently dilution with solvents is also variable and depends upon several to be selected factors, for example upon the type of application. The lacquer can, for example, be brought to a final solid matter contents of approximately 5 to 30% by means of solvents.
Excellent layer qualities are obtained with a lacquer which was brought by means of rotary incorporation to approximately 60 to 70% by weight of solid matter contents and was then diluted by solvents (for example Propylacetate) to a solid matter contents of approximately 10% by weight.
According to the invention, it is also possible to apply a second hydrophobic layer, for example of a fluorized hydrolyzed silane. Thus, a Perfluoralkl-triethoxysilane may be used.
Preferably, both these layers are jointly hardened (thermally and/or photo-chemically). Furthermore, th

Affiliated with

Also associated with

Rating

Hydrophobic coating for ink jet printing heads does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Hydrophobic coating for ink jet printing heads, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrophobic coating for ink jet printing heads will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2437229