Hydrophilic surface - modified polyolefin structures

Bleaching and dyeing; fluid treatment and chemical modification – Chemical modification of textiles or fibers or products thereof – Using wave energy – electrostatic field or electrical discharge

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811553, 811554, 81492, 8DIG9, 264 83, 428400, 428409, 5253339, 525344, 525355, C08F 836, C08F 838, D06B 1900, D06M 1100

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046664521

ABSTRACT:
A shaped polyolefin structure, such as a polyolefin fiber or a nonwoven web containing polyolefin fibers, is rendered hydrophilic by contacting the structure with a gaseous mixture of chlorine, sulfur dioxide, and oxygen or carbon monoxide or a mixture thereof, in the presence of a free radical-producing means. Such treatment results in the formation of hydrogen sulfato groups at the structure surface. Preferably, the hydrogen sulfato groups are converted to ammonium sulfato groups by subsequent treatment with ammonia or a sufficiently basic amine.

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patent: 4452953 (1984-06-01), Benedikt
patent: 4560731 (1985-12-01), Rifi
patent: 4584351 (1986-04-01), Blanchard
J. Mitchell, Jr. and L. R. Perkins, Applied Polymer Symposia, 1967, 167-173.

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