Hydrophilic fine gel particles and process for production thereo

Details Hydrophilic fine gel particles and process for production thereo Hydrophilic fine gel particles and process for production thereo

1990-07-24

1991-08-27

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

C08F22602

Patent

active

050434071

ABSTRACT:
Hydrophilic fine gel particles, said particles being crosslinked polymer particles comprising 20-94.8% by weight of a monoethylenically unsaturated amide monomer, 5-60.0% by weight of a crosslinkable ethylenically unsaturated monomer, 0.1-30% by weight of an ethylenically unsaturated carboxylic acid, 0.1-50% by weight of an ester monomer of an acrylic or methacrylic acid, and 0-30% by weight of a monomer copolymerizable with the above-mentioned monomers, said particles having a particle diameter in a water-swollen state of 0.1-10 .mu.m and a weight-average particle diameter
umber-average particle diameter ratio of 1.2 or less; and a process for producing hydrophilic fine gel particles having a particle diameter in a water-swollen state of 0.1-10 .mu.m and a weight-average particle diameter
umber-average particle diameter ratio of 1.2 or less, which comprises copolymerizing a monomer mixture of 20-94.8% by weight of a monoethylenically unsaturated amide monomer, 5-60.0% by weight of a crosslinkable ethylenically unsaturated monomer, 0.1-30% by weight of an ethylenically unsaturated carboxylic acid, 0.1-50% by weight of an ester monomer of an acrylic or methacrylic acid, and 0-30% by weight of a monomer copolymerizable with the above-mentioned monomers using a radical polymerization initiator in a solvent which dissolves these monomers but does not dissolve the resulting polymer.

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"Particle Size Control in Dispersion Polymerization of Polystyrene", Can. J. Chem., vol. 63, 1985, pp. 209-216.

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