Hydrophilic fine gel particles and process for production thereo

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

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5263076, B32B 516, C08F22602

Patent

active

049885685

ABSTRACT:
Hydrophilic fine gel particles, said particles being crosslinked polymer particles comprising 20-94.8% by weight of a monoethylenically unsaturated amide monomer, 5-60.0% by weight of a crosslinkable ethylenically unsaturated monomer, 0.1-30% by weight of an ethylenically unsaturated carboxylic acid, 0.1-50% by weight of an ester monomer of an acrylic or methacrylic acid, and 0-30% by weight of a monomer copolymerizable with the above-mentioned monomers, said particles having a particle diameter in a water-swollen state of 0.1-10 .mu.m and a weight-average particle diameter
umber-average particle diameter ratio of 1.2 or less; and a process for producing hydrophilic fine gel particles having a particle diameter in a water-swollen state of 0.1-10 .mu.m and a weight-average particle diameter
umber-average particle diameter ratio of 1.2 or less, which comprises copolymerizing a monomer mixture of 20-94.8% by weight of a monoethylenically unsaturated amide monomer, 5-60.0% by weight of a crosslinkable ethylenically unsaturated monomer, 0.1-30% by weight of an ethylenically unsaturated carboxylic acid, 0.1-50% by weight of an ester monomer of an acrylic or methacylic acid, and 0-30% by weight of a monomer copolymerizable with the above-mentioned monomers using a radical polymerization initiator in a solvent which dissolves these monomers but does not dissolve the resulting polymer.

REFERENCES:
patent: 3711574 (1973-01-01), Jaworek et al.
patent: 3929739 (1975-12-01), Barabes et al.
patent: 4722958 (1988-02-01), Sauer et al.
patent: 4748220 (1988-05-01), Hartmann et al.

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