Hydrometallurgical production of technical grade molybdic oxide

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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423 55, 423606, 423 50, 423 53, 423 54, 423 49, C01G 3900

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039884180

ABSTRACT:
An improved hydrometallurgical method is provided for producing technical grade molybdic oxide from molybdenite concentrates. According to this method, the molybdenite concentrates are leached in an acid medium having a nitric acid concentration between about 25 gpl and about 50 gpl and an initial sulphuric acid concentration of nil to about 750 gpl, under oxygen pressure of about 100 - 250 psig and at a temperature above 115.degree. C so as to produce technical grade molybdic oxide having not more than 0.1% sulphur. Then a liquid-solid separation of the reaction mixture is effected and the obtained leach liquor is recycled back to the leaching stage optionally after partial neutralization with a basic reagent. The solid is washed and recovered as technical grade molybdic oxide.

REFERENCES:
patent: 3739057 (1973-06-01), Daugherty et al.
Bjorling et al., "Journal of Chemistry, UAR", vol. 12, 1969, pp. 423-435.

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