Hydrolysis of water-insoluble organic halides

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568739, 568770, 568778, 568797, C07C 3702

Patent

active

045007403

ABSTRACT:
Secondary and tertiary alkyl halides, benzyl halides, and activated phenyl halides may be hydrolyzed in a 2-step procedure in good yield and under relatively mild conditions. The halide first is heated with dimethyl sulfoxide so as to form an intermediate or complex which is subsequently hydrolyzed with great facility upon contact with water, even at room temperature. The process is particularly applicable to water-insoluble organic halides.

REFERENCES:
patent: 2129907 (1938-09-01), Britton
patent: 2523707 (1950-09-01), Miller
patent: 2988573 (1961-06-01), Siebentritt et al.

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