Hydrolysis of halo- and alkyl-substituted phenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568765, 568766, 568770, 568774, C07C 3911, C07C 3927

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active

048495484

ABSTRACT:
A 4-halomethyl-3,5-dihalo-2,6-dialkylphenol is hydrolyzed by contact with water to form a 4-hydroxy-methyl-3,5-dihalo-2,6-dialkylphenol under conditions to minimize formation of the corresponding bis-(4-hydroxy-3,5-dialkyl-2,6-dihalobenzyl) ether.

REFERENCES:
patent: 4731423 (1988-03-01), Mondoza et al.
Mendoza et al., Meta-Halo-Phenolic Alkylation Products and Epoxy Systems, U.S. Pat. No. 4,731,423 (Mar. 15, 1988).
Auwers et al., "Ueber Anhydro-p-Oxymesitylalkohol und Seine Umwaldungsproduct", 302 Ann. Chemie 76 (1898) (Translation Attached).
Auwers et al., "Ueber Dibrom-p-Oxymesitylalkohol", 32 Berichte 3309 (1899) (Translation Attached).

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