Hydrolysis of activated olefinic ketones and aldehydes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568459, 568449, C07C 4542

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active

047090987

ABSTRACT:
Ketones or aldehydes containing one or more carbon-carbon double bonds and a carbonyl group conjugated with at least one double bond are hydrolyzed by the action of heat and pressure in the presence of water. The ketone or aldehyde cleaves at the double bond conjugated with the carbonyl group to produce additional carbonyl-containing compounds.

REFERENCES:
patent: 2613905 (1952-12-01), Pines
patent: 3833659 (1974-09-01), Schmerling et al.
Annalen, vol. 289, p. 337 (1896).

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