Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization
Patent
1979-06-28
1980-11-04
Crasanakis, George
Chemistry of hydrocarbon compounds
Saturated compound synthesis
By isomerization
C07C 530
Patent
active
042321816
ABSTRACT:
Ammonia exchanged large port mordenite, which is subsequently mildly acid leached, and calcined, in which at least 95% of the exchangeable sodium has been removed and having from 0.38 to 0.8 milliequivalents of acid sites at least as strong as 48% sulfuric acid per gram (as measured by titration with butylamine, and employing dicinnamalacetone indicator) has been found to be highly active hydrocarbon isomerization catalyst. Incorporation of noble metal, e.g. palladium, on the catalyst improves the selectivity for isomerization of normal pentane to isopentane for highly active catalysts at high conversion rates.
REFERENCES:
patent: 3190939 (1965-06-01), Benesi
patent: 3507931 (1970-04-01), Morris et al.
patent: 3574092 (1971-04-01), Mitsche
patent: 3836597 (1974-09-01), Sie
patent: 3842114 (1974-10-01), Sie
patent: 3932554 (1976-01-01), Takase et al.
Goyette William J.
Kiovsky Joseph R.
Crasanakis George
Franklin Rufus M.
Norton Company
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