Hydrogenolysis of hydrobenzoins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260600R, 260668R, 260613R, 260515R, 260515P, 260465R, 260465H, 260612R, 260649R, 560 57, 568729, 568723, C07C 4100, C07C 122

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040874630

ABSTRACT:
Hydrogenolysis of hydrobenzoins [1,2-bis(aryl)ethane-1,2-diols] in the presence of a catalyst comprising cobalt carbonyl yields 1,2-bis(aryl)ethanes. The process is particularly directed to the production of 1,2-bis(4-hydroxyphenyl)ethane from 4,4-dihydroxyhydrobenzoin [1,2-bis(4-hydroxyphenyl)ethane-1,2-diol].

REFERENCES:
Wender et al., J.A.C.S., vol. 73 (1951) 2656-2658.

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