Hydrogenolysis of halocarbon mixtures

Details Hydrogenolysis of halocarbon mixtures Hydrogenolysis of halocarbon mixtures

1992-12-29

1994-04-05

Siegel, Alan

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

C07C 1908

Patent

active

053007131

ABSTRACT:
Mixtures of halocarbons which contain fluorine and chlorine and/or bromine (e.g. a mixture of CCl.sub.2 FCF.sub.3 with CClF.sub.2 CF.sub.3, CCl.sub.2 F.sub.2, CClF.sub.2 CClF.sub.2 or CHClF.sub.2) are contacted with hydrogen in the presence of silicon carbide and/or a metal selected from aluminum, molybdenum, titanium, nickel, iron or cobalt (or their alloys) at temperatures of 350.degree. to 700.degree. C. and pressures of 0 to 1000 psig to obtain a product mixture which substantially corresponds in terms of the distribution of fluorine substituents on carbon atoms with the mixture of halocarbon starting materials.

REFERENCES:
patent: 2005708 (1935-06-01), Daudt et al.
patent: 2005710 (1935-06-01), Daudt et al.
patent: 2062748 (1936-12-01), Daudt, et al.
patent: 2146725 (1939-02-01), Dunphy
patent: 2615926 (1952-10-01), Benning et al.
patent: 2704775 (1955-03-01), Clark et al.
patent: 2748177 (1956-05-01), Miller et al.
patent: 3042727 (1962-07-01), Olstowski et al.
patent: 3138559 (1964-06-01), Hauptschein et al.
patent: 4155881 (1979-05-01), Sullivan
patent: 4319060 (1982-03-01), Cunningham et al.
patent: 5001283 (1991-03-01), Fernandez et al.
T. Fluorine Chem., 19, pp. 1-20, Gervasutti et al., Received Dec. 12, 1980.
J. Amer. Chem. Soc., 72, pp. 705-707, Miller et al., Feb. 1950.

Affiliated with

Also associated with

Rating

Hydrogenolysis of halocarbon mixtures does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Hydrogenolysis of halocarbon mixtures, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrogenolysis of halocarbon mixtures will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-512901