Hydrogenolysis of alcohols, ketones, aldehydes, esters and ether

Details Hydrogenolysis of alcohols, ketones, aldehydes, esters and ether Hydrogenolysis of alcohols, ketones, aldehydes, esters and ether

1975-08-25

1978-01-10

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260690, 260613R, C07C 6708

Patent

active

040679004

ABSTRACT:
The present invention relates to a process for the preparation of saturated hydrocarbons from alcohols, ketones, aldehydes, esters or ethers by hydrogenolysis in the presence of catalyst systems containing an iridium or rhodium component and a halogen component. The process is specifically directed to the production of methane from methanol, toluene from benzaldehyde, ethyl benzene from methyl benzyl alcohol or acetophenone, bis(p-hydroxyphenyl) ethane from anisoin.

REFERENCES:
patent: 3428661 (1969-02-01), Taylor
patent: 3489786 (1970-01-01), Dewhirst
patent: 3759838 (1973-09-01), Dewhirst

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