Hydrogenolysis of 5-carbon sugars, sugar alcohols, and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S861000, C568S852000, C568S868000

Reexamination Certificate

active

07038094

ABSTRACT:
Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.

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Zhang, Z., et al. “Aqueous-Phase Hydrogenation of Lactic Acid to Propylene Glycol.” p. 89-98. 2001.

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