Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl

Details Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl

1979-12-13

1981-07-14

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Compound or reaction product mixture

Alicyclic

60208, 1491094, C07C 1362

Patent

active

042788234

ABSTRACT:
Hydrogenolysis of a saturated endo-endo dihydronorbornadiene hexacyclic dimer involves the use of a catalytic amount of a Group VIII metal and the presence of hydrogen. The resulting pentacyclic isomers can be used as a diluent for depressing the freezing point of the saturated hexacyclic dimer which is a component of a high density missile fuel.

REFERENCES:
patent: 4207080 (1980-06-01), Suld et al.
M. N. Akhtar et al., J. Chem. Soc. Perkin II, 1412-1414, 1976.
H. A. Quinn et al., J. Catalysis, 26, 333-337, 1972.
M. N. Akhtar et al., J. Amer. Chem. Soc. 96, 276-277, 1974.
M. N. Akhtar et al., J. Chem. Soc. Comm., 155-156, 1974.
Thomas J. Katz et al., Tetrahedron Letters, 27, 2601-2605, 1967.
Nancy Acton, et al., J. Amer. Chem. Soc. 94, 5446-5456, 1972.

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