Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl

Details Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacycl

1978-09-15

1980-12-30

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

By shift, opening, or removal of shared-carbon ring

585360, 585 14, 149 1, C09C 1328

Patent

active

042425298

ABSTRACT:
Hydrogenolysis of a saturated endo-endo dihydronorbornadiene hexacyclic dimer involves the use of a catalytic amount of a Group VIII metal and the presence of hydrogen. The resulting pentacyclic isomers can be used as a diluent for depressing the freezing point of the saturated hexacyclic dimer which is a component of a high density missile fuel.

REFERENCES:
M. Naseem Akhtar et al., J. Chem. Soc. Perkin II pp. 1412-1414, 1976.
Thomas J. Katz et al., Chem. Ab. 70:87128q, 1969.
Nancy Acton et al., J. Amer. Chem. Soc. 94:15, 5446-5456, 1972.
Thomas J. Katz et al., Tetrahedron Letters, No. 27, pp. 2601-2605, 1967.
M. N. Akhtar et al., J. Amer. Chem. Soc. 96:1 pp. 276-277, 1974.
H. A. Quinn et al., J. of Catalysis 26, 333-337, 1972.
M. N. Akhtar et al., J. Chem. Soc. Chem. Comm. pp. 155-156, 1974.

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