Hydrogenolysis/dehydrohalogenation process

Details Hydrogenolysis/dehydrohalogenation process Hydrogenolysis/dehydrohalogenation process

1991-06-26

1992-09-08

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

546345, 570143, 570176, C07C 1724, C07C 1734, C07C 1908, C07C 2113

Patent

active

051460181

ABSTRACT:
A process for the hydrogenolysis and/or dehydrohalogenation of fluorohalocarbons and/or fluorohalohydrocarbons by reacting the fluorohalocarbons and/or fluorohalohydrocarbons with a source of hydrogen in the presence of a catalyst, the improvement comprising utilizing a rhenium-containing catalyst, which may, optionally, contain at least one Group VIII metal and may, optionally, be supported.

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Morrison and Boyd "Organic Chemistry" 3rd ed. (1973) pp. 156-159.
C. Gervasutti et al., J. Fluorine Chem., 19, 1 (1981).

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