Hydrogenation of phthalonitriles using rhodium catalyst

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252477Q, C07C 8502

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active

039988813

ABSTRACT:
A process for the preparation of 1,3 or 1,4-bis (aminomethyl)cyclohexane by hydrogenating a solvent solution of iso- or terephthalonitrile at a temperature between about 50.degree. and about 150.degree. C., at a pressure of between about 500 and about 1500 psig., and in the presence of a supported rhodium catalyst.

REFERENCES:
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patent: 3372195 (1968-03-01), Little
patent: 3673251 (1972-06-01), Frampton et al.
patent: 3739009 (1973-06-01), Sturm et al.
patent: 3880928 (1975-04-01), Drake
Takagi et al. "Hydrogenation of Nitriles Catalyzed by Platinum Metals" in Sci. Pap. Inst. Phys. Chem. Res. (Tokyo), 61(3), 114-117, 1967.

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