Hydrogenation of nitriles to produce amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564415, 564490, C07C20948

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055741894

ABSTRACT:
This invention relates to an improvement in a process for the production of amines and particularly secondary amines by the hydrogenation of aliphatic and aromatic nitriles. The improvement resides in the use of a multi-metallic catalyst, preferably a bimetallic catalyst comprising nickel or cobalt in combination with rhodium, ruthenium or palladium. Optionally, the catalyst is carried on an alumina support.

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patent: 5254737 (1993-10-01), Zimmerman
Volf, Jiri and Josef Posek "Hydrogenation of Nitriles" Studies in Surface Science & Catalysis, vol. 27 pp. 105-144 1986.

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