Hydrogenation of aromatic amines to alicyclic amines using a...

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C564S451000

Reexamination Certificate

active

07465833

ABSTRACT:
The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalyst under temperature and pressure conditions suitable to effect ring hydrogenation. The process is especially useful for hydrogenating aniline to cyclohexylamine.

REFERENCES:
patent: 2511028 (1950-06-01), Whitman
patent: 2606924 (1952-08-01), Whitman
patent: 2606925 (1952-08-01), Whitman
patent: 2606928 (1952-08-01), Barkdoll et al.
patent: 2822392 (1958-02-01), Illich, Jr. et al.
patent: 3636108 (1972-01-01), Brake
patent: 3644522 (1972-02-01), Brake et al.
patent: 3697449 (1972-10-01), Brake
patent: 3959374 (1976-05-01), Brennan et al.
patent: 4448995 (1984-05-01), Allen
patent: 4946998 (1990-08-01), Casey et al.
patent: 5023226 (1991-06-01), Immel et al.
patent: 5773657 (1998-06-01), Ruetter et al.
patent: 6184416 (2001-02-01), Ding et al.
patent: 21 32 547 (1982-11-01), None
patent: 38 01 755 (1988-01-01), None
patent: 42 07 314 (1993-09-01), None
patent: 1604972 (2005-12-01), None
patent: 1630155 (2006-03-01), None
Narayanan, S., et al., “Comparison of Hydrogen Adsorption and Aniline Hydrogenation Over Co-Precipitated Co/Al2O3and Ni/Al2O3Catalysts,” Catalysts Section, Indian Institute of Chemical Technology, Hyderabad—500007, India,J. Chem. Soc., FaradayTrans.,vol. 93, pp. 2009-2013 (1997).
Vishwanathan, V., et al., “A Direct Correlation Between Dispersion, Metal Area, and Vapour Phase Hydrogenation of Aniline; a First Report,”J. Chem.Soc., Chem. Commun.,pp. 78-80 (1990).
Narayanan, S., et al., “Nickel-Alumina Prepared by Constant and Varying pH Method: Evaluation by Hydrogen-Oxygen Chemisorption and Aniline Hydrogenation,”Applied Catalysis A: General,vol. 129 (1), pp. 9-19 (1995).
Vishwanathan, V., et al., “Gas Phase Aniline Hydrogenation Over Supported Rhodium/Alumina Catalyst,”Indian Journal of Chemistry,vol. 30A, pp. 679-681 (1991).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Hydrogenation of aromatic amines to alicyclic amines using a... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Hydrogenation of aromatic amines to alicyclic amines using a..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrogenation of aromatic amines to alicyclic amines using a... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4041598

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.