Hydrogenation of .alpha.-pinene to cis-pinane

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Using transition metal-containing catalyst

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585277, 585350, 585947, C07C 503, C07C 1347

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active

043107141

ABSTRACT:
Ruthenium has been found to be a stereoselective catalyst for the hydrogenation of .alpha.-pinene to obtain cis-pinane.

REFERENCES:
patent: 4018842 (1977-04-01), Cavova
patent: 4204080 (1980-05-01), Bledsoe et al.
patent: 4261927 (1981-04-01), Drake
Berkowitz and Rylander, J. Org. Chem., 24, 708, (1959).

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