Hydrogenation method for unsaturated block copolymers and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S330300, C525S332800, C525S332900, C525S339000

Reexamination Certificate

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10466170

ABSTRACT:
Use is made, for selectively hydrogenating the olefinic double bonds of block copolymers, at least one block of which comprises olefinic double bonds, using a catalyst based on a metal from Group VIII in a medium comprising an organic solvent for the copolymer and an ionic liquid as solvent for the catalyst, of a water-immiscible ionic liquid, preferably an ionic liquid for which the anion is the hexafluorophosphate anion and the cation is the 1-butyl-3-methylimidazolium (bmim+) or 1-ethyl-3-methylimidazolium (emim+) cation.Applied to poly(styrene)-b-poly(butadiene)-b-poly(methyl methacrylate) block copolymers, the poly(butadiene) block of which predominantly possesses a 1,4-microstructure, this process results in copolymers for which the degree of hydrogenation is at least equal to 50% and which exhibit a melting point of greater than 30 °C.

REFERENCES:
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International Search Report (Form PCT/ISA/210), issued for PCT/FR01/03703.
Muller L A et al., “Two-phase catalytic NBR hydrogenation by RuHCI(CO) (Pcy3)2 immobilized in 1-butyl-3-methylimidazolium tetrafluoroborate molden salt”, Macromol. Rapid Communl, vol. 19, No. 8, 1998, pp. 409-411.
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Vittoria Balsamo, et al., “Ternary ABC block copolymers based on one glassy and two crystallizable blocks: polystyrene-block-polyethylene-block-poly(ε-caprolactone)”, Macromol. Phys. 199, pp. 1063-1070 (1998).
Paulo A. Z. Suarez, et al., “Communication—The Use of New Ionic Liquids in Two-Phase Catalytic hydrogenation Reaction by Rhodium Complexes”, Polyhedron, 15, No. 7 (1996), pp. 1217-1219.
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Translation of European Patent No. 0 672 085, which is the English-language equivalent of DE 42 40 445 (filed in IDS on Jan. 29, 2004).

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