Chemistry of inorganic compounds – Oxygen or compound thereof – Peroxide
Patent
1999-05-19
2000-10-03
Langel, Wayne
Chemistry of inorganic compounds
Oxygen or compound thereof
Peroxide
C01B 15023
Patent
active
06126914&
ABSTRACT:
A hydrogenation catalyst for the production of hydrogen peroxide by the hydrogenation of anthraquinones in accordance with a hydrogen peroxide production process utilizing an anthraquinone method. The catalyst includes palladium supported on a carrier. The carrier comprises spherical silica particles, wherein at least 90 wt % of the silica particles have particle diameters of 10 to 100 .mu.m. The silica particles have an average particle diameter of 30 to 60 .mu.m and a pore volume of 0.4 to 1.0 ml/g. The catalyst has desirable activity, strength, service life and selectivity.
REFERENCES:
patent: 2657980 (1953-11-01), Sprauer
patent: 2837411 (1958-06-01), Jenney
patent: 2867507 (1959-01-01), Gleason et al.
patent: 2940833 (1960-06-01), Le Feuvre et al.
patent: 3668148 (1972-06-01), Van Beek et al.
patent: 3694376 (1972-09-01), Kabisch et al.
patent: 3700745 (1972-10-01), Kouach et al.
patent: 3853786 (1974-12-01), Forni et al.
patent: 4192777 (1980-03-01), McVicker et al.
patent: 4258025 (1981-03-01), Copelin
patent: 4289709 (1981-09-01), Kaiser
patent: 4428922 (1984-01-01), Hopkins
patent: 4521531 (1985-06-01), Coates
patent: 4522748 (1985-06-01), Maurer et al.
patent: 4608362 (1986-08-01), Darke
patent: 5053377 (1991-10-01), Lerot et al.
patent: 5110779 (1992-05-01), Hucul
patent: 5114902 (1992-05-01), Schwarz et al.
patent: 5122496 (1992-06-01), Vorlop et al.
patent: 5342603 (1994-08-01), Deremince et al.
patent: 5399333 (1995-03-01), Kato et al.
patent: 5772977 (1998-06-01), Jenkins et al.
patent: 5776240 (1998-07-01), Deller et al.
Santacesaria et al.,, "Kinetics, Mass Transfer, and the Palladium Catalyst Deactivation in the Hydrogenation Step of the Hydrogen Peroxide Synthesis via Anthraquinone", Ind. Eng. Chem. Res., 33, pp. 277-284 (1994).
Santacesaria et al., "Hydrogenation of 2-Ethyltetrahydroanthraquinone in the Presence of Palladium Catalyst", Ind. Eng. Chem. Res., 27, pp. 780-784 (1988).
Fukuma et al., "Specific Gas-Liquid Interfacial Area and Liquid-Phase Mass Transfer Coefficient in a Slurry Bubble Column", Jour. of Chem. Engineering of Japan, 20, No. 3, pp. 321-324 (1987).
Kato Kenji
Kato Tomio
Konishi Tetsuya
Ogasawara Kazuharu
Okuda Norikazu
Langel Wayne
Mitsubishi Gas Chemical Co. Inc.
LandOfFree
Hydrogenation catalyst for production of hydrogen peroxide, and does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Hydrogenation catalyst for production of hydrogen peroxide, and , we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrogenation catalyst for production of hydrogen peroxide, and will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-192172