Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making
Patent
1993-06-15
1995-05-23
Lieberman, Paul
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Silicon containing or process of making
502324, B01J 2384, B01J 2334, B01J 2104, B01J 3703
Patent
active
054182018
ABSTRACT:
In one embodiment, the invention relates to a catalyst in powdered form comprising the oxides of copper, iron, aluminum and manganese wherein the atomic ratio of copper to iron is at least 1:1. In another embodiment, the invention relates to a process for preparing such hydrogenation catalysts which comprises the steps of
(A) preparing a first aqueous solution containing at least one water-soluble copper salt, at least one water-soluble iron salt, and at least one water-soluble manganese salt;
(B) preparing a second solution containing at least one water-soluble basic aluminum salt and at least one alkaline precipitating agent;
(C) mixing the first and second solutions wherein an insoluble solid is formed;
(D) recovering the soluble solid; and
(E) calcining the recovered solid to form the desired catalyst.
The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters.
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Plundo Robert A.
Roberts Brian D.
Sullivan Thomas J.
Thakur Deepak S.
Engelhard Corporation
Lieberman Paul
McGinty Douglas J.
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