Hydrogen transfer by metal hydride between aqueous medium and or

Details Hydrogen transfer by metal hydride between aqueous medium and or Hydrogen transfer by metal hydride between aqueous medium and or

1977-06-09

1978-10-17

Edmundson, F.C.

Chemistry: electrical and wave energy

Processes and products

204291, 204 76, C25B 304, C25B 1104

Patent

active

041207637

ABSTRACT:
A process for the transfer of hydrogen to or from an organic compound comprises introducing the organic compound into an electrolysis cell containing an aqueous electrolyte and at least one working electrode consisting of a metal hydride and a counterelectrode spaced from the working electrode. An electrolysis current is passed through the cell to remove hydrogen from the metal hydride or introduce hydrogen to the metal hydride in equilibrium with the reaction with the organic compound so that evolution of gaseous hydrogen is prevented. The metal hydride consists of a first component selected from the group of titanium, zirconium, lanthanum and palladium and at least one second component selected from the group which consists of iron, nickel, cobalt, copper, chromium, manganese, vanadium, niobium and silver.

REFERENCES:
patent: 3382106 (1968-05-01), Jung et al.
patent: 3617462 (1971-11-01), DeWitt
patent: 3879271 (1975-04-01), Nohe et al.
patent: 3880731 (1975-04-01), Rusakova et al.

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