Chemistry of inorganic compounds – Nitrogen or compound thereof – Hydrogen containing
Reexamination Certificate
2011-01-04
2011-01-04
Lorengo, Jerry (Department: 1793)
Chemistry of inorganic compounds
Nitrogen or compound thereof
Hydrogen containing
C423S648100, C423S644000, C423S645000, C423S646000, C423S647000, C423S658200
Reexamination Certificate
active
07862791
ABSTRACT:
In one aspect, the invention provides a hydrogen storage material that is formed by reacting solid precursors (a) and (b). The (a) precursor is a compound containing X—H and Y—H bonds, where X is a Group 13 and Y is a Group 15 element. Preferably X is boron (B—H) and Y is nitrogen (N—H). Most preferably, the precursor (a) is borazane. The (b) precursor is preferably a hydride, such as LiH or LiAlH4. Another feature of the present invention is a novel hydrogen storage composition material that is formed as an intermediate (INT) in the reaction of the (a) with the (b) precursors. The INT hydrogen storage material can be a quaternary B—H—Li—N composition. Other aspects of hydrogen storage materials are provided herein.
REFERENCES:
patent: 3821044 (1974-06-01), Roberts
patent: 4007257 (1977-02-01), Lemieux et al.
patent: 6015041 (2000-01-01), Heung
patent: 6159538 (2000-12-01), Rodriguez et al.
patent: 6267229 (2001-07-01), Heung
patent: 6329076 (2001-12-01), Kawabe et al.
patent: 6342198 (2002-01-01), Zaluska et al.
patent: 6419764 (2002-07-01), Kamiya et al.
patent: 6432379 (2002-08-01), Heung
patent: 6444361 (2002-09-01), Komori et al.
patent: 6468487 (2002-10-01), Ishii et al.
patent: 6528441 (2003-03-01), Heung et al.
patent: 6773692 (2004-08-01), Pecharsky et al.
patent: 6929679 (2005-08-01), Muller et al.
patent: 6946112 (2005-09-01), Chen et al.
patent: 6967012 (2005-11-01), Meisner et al.
patent: 7029649 (2006-04-01), Meisner et al.
patent: 7166150 (2007-01-01), Torgersen et al.
patent: 7214360 (2007-05-01), Chen et al.
patent: 7214439 (2007-05-01), Ortega et al.
patent: 7279222 (2007-10-01), Hearley et al.
patent: 7314579 (2008-01-01), Pinkerton et al.
patent: 7316788 (2008-01-01), Autrey et al.
patent: 7341703 (2008-03-01), Pinkerton et al.
patent: 7344690 (2008-03-01), Meisner et al.
patent: 7537747 (2009-05-01), Meyer et al.
patent: 7601329 (2009-10-01), Vajo et al.
patent: 2003/0113252 (2003-06-01), Chen et al.
patent: 2003/0129126 (2003-07-01), Chen et al.
patent: 2003/0180587 (2003-09-01), Jones et al.
patent: 2004/0005265 (2004-01-01), Chiang et al.
patent: 2005/0069487 (2005-03-01), Zhao et al.
patent: 2005/0106097 (2005-05-01), Graham et al.
patent: 2005/0191236 (2005-09-01), Pinkerton et al.
patent: 101027246 (2007-08-01), None
patent: 101184689 (2008-05-01), None
patent: 112005002271 (2007-08-01), None
patent: 112005002272 (2007-08-01), None
patent: 20070055619 (2007-05-01), None
patent: WO 02/18267 (2002-03-01), None
patent: WO 2006/036553 (2006-04-01), None
patent: WO 2006/036554 (2006-04-01), None
Vong et al. “Synthetic studies on borrelidin: Enantioselective synthesis of C1-C12 Fragment”, Feb. 2003, Organic letters, vol. 5, No. 10 1617-1620.
Baitalow, F. et al. “Thermal Decomposition of B-N-H Compounds Investigated by Using Combined Thermoanalytical Methods” Thermochimica Acta, vol. 391 (2002), pp. 159-168.
Hu, M.G. et al. “The Thermal Decomposition of Ammonia-Borane” Thermochimica Acta, vol. 23 (1978), pp. 249-255.
Morinaga, M. et al. “Roles of Constituent Elements and Design of Hydrogen Storage Alloys” Journal of Alloys and Compounds, vol. 330-332 (2002), pp. 20-24.
Ruff, John et al. “The Amine Complexes of Aluminum Hydride. I” J. Am. Chem. Soc., vol. 82 (May 5, 1960), pp. 2141-2144.
Ruff, John et al. “The Amine Complexes of Aluminum Hydride. II” J. Am. Chem. Soc., vol. 83 (Feb. 5, 1961), pp. 535-538.
Wiberg, Von Egon et al. “Uber die Umsetzung von Aluminiumwasserstoff mit Ammoniak and Aminem”, Z. Naturforsch, vol. 10B (1955), pp. 229-235.
Wolf, G. et al. “Calorimetric Process Monitoring of Thermal Decomposition of B-N-H Compounds” Thermochimica Acta, vol. 343 (2000), pp. 19-25.
Wolf, G. et al. “Thermochemical Investigations on Borazane (BH3-NH3) in the Temperature Range from 10 to 289 K” Thermochimica Acta, vol. 317 (1998), pp. 111-116.
Aldrich Chemical Company Order Catalogue, Borane-Ammonia Complex (1994), p. 195.
International Search Report for PCT/US05/32699 dated Jun. 29, 2007 and corresponding to this application.
Korean Office Action issued Jun. 26, 2008 in related Korean Patent Application No. 10-2007-009248 (4 pages) and the English translation (4 pages).
Cenzual et al., “Inorganic Structure Types with Revised Space Group,” Acta Cryst., vol. B47 pp. 433-439 (1991).
Chen et al., “Hydrogen Storage in Metal Nitride Systems,” Edited by Ricardo B. Schwartz, Symposium V, Materials for Energy Storage, Generation and Transport, vol. 730 pp. 376 and 385 (Apr. 2-4, 2002).
Chen et al., “Interaction of Hydrogen with Metal Nitrides and Imides,” Nature Publishing Group, vol. 420, pp. 302-304 with Supplement pp. 1-6 (Nov. 21, 2002).
Goubeau, et al., “Über ternäre Metall-Bornitride,” Zeitschrifte für anorganishe and allgewieine, Chemic vol. 310, pp. 248-260 (1961).
Hu et al., “Ultrafast Reaction between LiH and NH3during H2Storage in Li3N,” J. Phys. Chem. A; vol. 107, No. 46, pp. 9737-9739 (Nov. 20, 2003).
Ichikawa et al., “Mechanism of Novel Reaction for LiNH and LiH to Li2NH and H2as a Promising Hydrogen Storage System,” J. Phys. Chem. B; vol. 108, No. 23, pp. 7887-7892 (May 5, 2004).
Jacobs et al., “Preparations and Properties of Magnesium Amide and Imide,” Journal for Anorganic and General Chemistry, Band, vol. 870, pp. 254-261 (1969). (English translation only; original German not available).
JCPDS X-Ray Database; pattern No. 00-007-0245—Li3AlN2.
JCPDS X-Ray Database; pattern No. 00-036-1016—β-Mg3B2N4.
JCPDS X-Ray Database; pattern No. 00-042-0868—Mg3BN3.
JCPDS X-Ray Database; pattern No. 00-044-1497—Mg3BN3.
JCPDS X-Ray Database; pattern No. 16-273—Li3BN2.
JCPDS X-Ray Database; pattern No. 40-1166—Li3BN2.
JCPDS X-Ray Database; pattern No. 80-2274—Li3BN2.
Juza et al., “Die ternären Nitride Li3AlN2and Li3GaN2,” Zeitschrifte für Anorganische Chemic, vol. 257, pp. 13-25 (1948).
Juza et al., “Metal amides and metal nitrides,” 25thPart, Journal for Anorganic and General Chemistry, vol. 266, pp. 325-330 (1951). (English translation and German language document).
Pinkerton et al., “Hydrogen Desorption Exceeding Ten Weight Percent from the New Quaternary Hydride Li3BN2H8,” ACS Publications, http://pubs.acs.org/cgi-bin/abstract.cgi/jpcbfk/2005/109/i01/abs/jp0455475.html.
Pinkerton et al., “Bottling the Hydrogen Genie,” The Industrial Physicist, pp. 20-23 (Feb./Mar. 2004).
Villars et al., “ASM International Handbook of Ternary Alloy Phase Diagrams,” Al Li N; AlLi3N2(1) Crystallographic Data (1997).
Villars et al., “ASM International Handbook of Ternary Alloy Phase Diagrams,” B Li N; BLi3N2(LT) (2) Crystallographic Data (1997).
Villars et al., “ASM International Handbook of Ternary Alloy Phase Diagrams,” B Li N; BLi3N2(HT) (2) Crystallographic Data (1997).
Villars, P., “Pearson's Handbook Desk Edition,” Crystallographic Data for Intermetallic Phases, Ac—Cr2Se4Zr, vol. 1, p. 416, p. 771 and p. 776 (1997).
Yamane et al., “High- and Low-Temperature Phases of Lithium Boron Nitride, Li3BN2Preparation, Phase Relation, Crystal Structure, and Ionic Conductivity,” J. Solid State Chemistry, vol. 71, pp. 1-11 (1987).
Yamane et al., “Structure of a New Polymorph of Lithium Boron Nitride, Li3BN2,” J. Solid State Chemistry, vol. 65, pp. 6-12 (1986).
Non-final Office Action issued on Jan. 20, 2010 in related U.S. Appl. No. 11/226,065.
Non-final Office Action issued on Aug. 13, 2009 in related U.S. Appl. No. 11/226,065.
Non-final Office Action issued on Jan. 27, 2009 in related U.S. Appl. No. 11/226,065.
Restriction/Election of Species Requirement issued on Dec. 30, 2009 in related U.S. Appl. No. 11/743,826.
Jorgensen Scott W.
Siporin Stacey E.
Torgersen Alexandra N.
Abu Ali Shuangyi
GM Global Technology Operations Inc.
Harness & Dickey & Pierce P.L.C.
Lorengo Jerry
LandOfFree
Hydrogen storage systems and compositions does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Hydrogen storage systems and compositions, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrogen storage systems and compositions will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2664530