Hydrogen storage material

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

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420416, 420900, 423644, C22C 3800

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045766401

ABSTRACT:
A hydrogen storage material for releasably storing hydrogen having a microstructure containing an alloy phase of the general formula R.sub.2 Fe.sub.17, wherein R is cerium and lanthanum and, optionally, at least one other rare earth element, and wherein a microstructure also contains from about 2 to 35% by weight, based on the total weight of all phases, of a eutectic of the formula R'/R'Fe.sub.2, wherein R' is lanthanum-starved R; the alloy phase of the general formula R.sub.2 Fe.sub.17 being present in an amount of not less than 40% by weight of the material, and the material contains less than 60% by weight of cerium based on the total amount of cerium, lanthanum and, if present, at least one other rare earth element. A method for producing such material by heat treating in an inert atmosphere so as to homogenize same and to increase the proportion of alloy phase in the material is also described.

REFERENCES:
Van Mal H. H. et al. "Hydrogen Absorption of Rare Earth (3d) Transition Intermetallic Compounds" J. Less Comm. Metals 49(1976) pp. 473-475.
Ray A. E. "Iron-Rare Earth Intermediate Phases" Proc. Rare Earth Res. Conf. 1968 CA 41399d.

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