Chemistry of inorganic compounds – Hydrogen or compound thereof
Patent
1992-05-08
1994-04-19
Lewis, Michael
Chemistry of inorganic compounds
Hydrogen or compound thereof
420900, 420588, 420580, 420424, 420417, 420421, 429207, C01B 600, H01M 400
Patent
active
RE0345881
ABSTRACT:
Four groups of advanced hydrogen hydride storage and hydride electrode materials, consisting of two common elements, titanium and nickel. In the first group of materials, zirconium and chromium are added with the common elements. The second group of materials contain three additional elements in addition to the common elements, namely, chromium, zirconium and vanadium. The third group of materials contain also, in addition to the common elements, zirconium and vanadium. The fourth group of materials adds manganese and vanadium with the common elements. The preparation methods of the materials, as well as their hydride electrode are disclosed. Electrochemical studies indicate that these materials have high capacity, long cycle life and high rate capability.
REFERENCES:
patent: 3660082 (1972-05-01), Negishi et al.
patent: 3669745 (1972-06-01), Beccu et al.
patent: 3824131 (1974-07-01), Beccu et al.
patent: 4075312 (1978-02-01), Tanaka et al.
patent: 4111689 (1978-09-01), Liu et al.
patent: 4112199 (1978-09-01), Dunlop et al.
patent: 4160014 (1979-07-01), Gamo et al.
patent: 4195989 (1980-04-01), Gamo et al.
patent: 4370163 (1983-01-01), Moriwaki et al.
patent: 4440736 (1984-04-01), Maeland et al.
patent: 4457891 (1984-07-01), Barnauer et al.
patent: 4487817 (1984-12-01), Williams et al.
patent: 4551400 (1985-11-01), Sapru et al.
patent: 4716088 (1987-12-01), Reichman et al.
patent: 4728586 (1988-03-01), Vankatesan et al.
patent: 4851299 (1989-07-01), Godziemba-Maliszewski
patent: 4946646 (1990-08-01), Gamo et al.
T. Schober & H. Wenzl, "The Systems NbH(D), TaH(D), VH(D): Structures, Phase Diagrams, Morphologies Method of Preparation", Hydrogen in Metals II, (1978), pp. 11-23.
D. Rohy & R. M. Cotts, "Electronic Specific Heat of Vanadium Chromium Hydride", Physical Review, vol. 1, No. 6, pp. 2484-2487, (Mar. 15, 1970).
Justi et al., "Electrocatalysis in the Nickel-Titanium System", Energy Conversion, vol. 10, pp. 183-187, (Mar. 1970).
Gujalar, Buchner & Beccu, "A New Type of Reversible Negative Electrode for Alkaline Storage Batteries Based on Metal Alloy Hydrides", 8th Int. Power Sources Conference, (1973), pp. 79-91.
Labaton, Garner & Whitehead, "Phase & Equilibrium Pressure Studies of the Zr-Ti-H System", J. Inorg. Nucl. Chem., vol. 24, pp. 1197-1204, (Apr. 1962).
Libowitz, "Effect of Thermal Gradients on Metal-Gas Systems", Atomic International, vol. 62, pp. 296-298, (Mar. 1958).
Korst, "The Crystal Structure of NiZrH.sub.3 ", Atomics International, vol. 66, pp. 370-372, (Feb. 1962).
Shaltiel, Jacob & Davidov, "Hydrogen Absorption & Desorption Properties of AB.sub.2 Laves Phase Pseudobinary Compound", Journal of the Less-Common Metals, vol. 53, pp. 117-131 (1977).
Jacob, et al., "Hydrogen absorption in (Zr.sub.x Ti.sub.1-x)B.sub.2 (B.tbd.Cr, Mn) and the Phenomen. Model for the Absorption Capacity in Pseudo-Binary Laves-Phase Compounds", Journal of the Less-Common Metals, vol. 73, pp. 369-376 (1980).
Jacob, Shaltiel, et al., "A Phenomen. Model for the Hydrogen Absorption Capacity in Pseudobinary Laves Phase Compounds", Solid State Communications, vol. 23, pp. 669-672 (1977).
Reilly & Wiswall, "The Higher Hydrides of Vanadium & Niobium", Inorganic Chemistry, vol. 9, No. 7, pp. 1678-1682 (1970).
Wakao, et al., "Electrochemical Capacities & Corrosion of TiNI.sub.x and its Zirconium-Substituting Alloy Hydride Electrodes", Journal of Less-Common Metals, vol. 104, pp. 365-373 (1984).
Bronoel, Sarradin & Bonnemay et al., "A New Hydrogen Storage Electrode", International Journal of Hydrogen Energy, vol. 1, pp. 251-254 (1976).
Gamo, Yamashita et al., "Ti-Mn Alloy Systems for Hydrogen Storage Material", National Technical Report, vol. 25, No. 5 (1979).
Wiswall, "Hydrogen Storage in Metals", Hydrogen in Metals II (1978), pp. 201-242.
Van Essen & Buschow, "Hydrogen Absorption in Various Zr-Hf based Intermetallic Compounds", Journal of Less Common Metals, vol. 64, pp. 277-284 (1979).
Van Essen & Buschow, "Composition & Hydrogen Absorption C14 type Zr-Mn Compounds", Mat. Res. Bull., vol. 15, pp. 1149-1155 (1980).
Pourarian, Sinha et al., "Kinetics & Thermodynamics of ZrMn.sub.2 -based Hydrides", Journal of Less Common Metals, vol. 88, pp. 451-458 (1982).
Oesterreicher & Bittner, "Studies of Hydride Formation in Ti.sub.1-x Zr.sub.x Mn.sub.2 ", Mat. Res. Bull., vol. 13, pp. 83-88 (1978).
Sinha, Pourarian & Wallace, "Hydrogenation Characteristics of Zr.sub.1-x Ti.sub.x MnFe Alloys", Journal of the Less Common Metals, vol. 87, pp. 283-296 (1982).
Pourarian & Wallace, "Anomalies in the Behavior of the Non-Stoichiometric Systems ZrMn.sub.2 T.sub.0.8 ", Solid State Communications, vol. 45, pp. 223-225 (1983).
Sinha, "Hydrides of ZrMn.sub.2 -Based Alloys Substoichiometric in Zr for Engineering Applications", Journal of the Less Common Metals, vol. 106, pp. 199-210 (1985).
Sinha, Yu & Wallace, "Hydrogen Storage in Some Ternary & Quaternary Zr-Based Alloys with the C14 Structure", Journal of Less Common Metals, vol. 106, pp. 67-77 (1985).
Lynch, Reilly & Millot, "The Absorption of Hydrogen by Binary V-Cr Alloys", J. Phys. Chem. Solids, vol. 39, pp. 883-890 (1978).
Pourarian & Wallace, "Hydrogen Sorption Characteristics of Zr.sub.1-x Ti.sub.x (Cr.sub.1-y Fe.sub.y).sub.2 Alloys", Journal of Less Common Metals, vol. 107, pp. 69-78 (1985).
Pourarian, Sinha & Wallace, "Hydrogen Sorption Properties of Non-Stoichiometric ZnMn.sub.2 -Based Systems", vol. 96, pp. 237-248 (1984).
Libowitz, Hayes & Gibbs, "The System Zr-Ni & Hydrogen", J. Phys. Chem., vol. 62, pp. 76-79 (1958).
Aoki & Masumoto, "Hydrogen Sorption & Desorption Properties of Amorphous Ti-Ni & Hf-Ni Alloys", Journal of Less Common Metals, vol. 113, pp. 33-41 (1985).
Machida, et al., "A Study of the Amorphous Ni.sub.0.33 Ti.sub.0.67 & Ni.sub.0.33 Zr.sub.0.67 Alloy Cathodes for Water Electrolysis Using Electron Spectroscopy for Chemical Analysis", Journal of Less Common Metals, vol. 96, pp. 305-313 (1984).
Van Rijswick, "Metal Hydride Electrodes for Electrochemical Energy Storage", Hydrogen for Energy Storage, (1977), pp. 261-271.
Proceedings of 11th Rare Earth Conference, Hydrogen in Rare Earth Intermetallics, Buechow et al., Oct. 1974.
The Effect of Aluminum Additions on the Structural and Hydrogen Absorption Properties of AB.sub.5 Alloys with Particular Reference to the LaNi.sub.5 Al.sub.0.5 Ternary Alloy System, Mendelsohn et al., Journal of the Less Common Metals, 63, 1979, pp. 193-207.
Hydrogen Absorption in LaNi.sub.5 and Related Compounds: Experimental Observations and their Explanation, Van Mal et al., Journal of the Less Common Metals, 35, (1974), pp. 65-76.
Equilibrium Studies on the Systems ZrCr.sub.2 -H.sub.2, ZrV.sub.2 -H.sub.2 and ZrMo.sub.2 -H.sub.2 Between 0.degree. and 900.degree. C., Pepler et al., Transactions of the Metallurgical Society of AIME, 237, (1967), pp. 1593-1600.
Bos Steven
Lewis Michael
LandOfFree
Hydrogen storage hydride electrode materials does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Hydrogen storage hydride electrode materials, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hydrogen storage hydride electrode materials will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-12774