Hydrogen recovery by adsorbent membranes

Gas separation: processes – Selective diffusion of gases – Selective diffusion of gases through substantially solid...

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95 50, 95 51, 95 96, 95139, 95143, B01D 53047, B01D 5322

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054358361

ABSTRACT:
Recovery of hydrogen from hydrogen-containing gas mixtures by pressure swing adsorption is increased by utilizing an adsorbent membrane to concentrate hydrogen in the pressure swing adsorption reject gas and recycling the resulting hydrogen-enriched stream to the feed of the pressure swing adsorption system. Lower compression requirements are realized compared with the use of polymeric membranes for the same service because the hydrogen-enriched stream is recovered from the adsorbent membrane as nonpermeate at essentially the membrane feed pressure. Simultaneous permeation of carbon dioxide and methane occur in the adsorbent membrane, which can be operated at feed pressures as low as 5 psig when hydrogen is used as a sweep gas.

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