Hydrogen peroxide based ECL

Details Hydrogen peroxide based ECL Hydrogen peroxide based ECL

1998-08-20

2000-10-24

Tucker, Philip

Compositions

Chemiluminescent

252583, 2525192, 25251921, 25230118, 2524081, 435 4, 435 5, 435 6, 436805, C09K 300, C09K 1106, C12Q 100

Patent

active

061362336

ABSTRACT:
An electrochemiluminescence (ECL)-based assay for the quantitation of classical clinical chemistry analytes, where glucose, ethanol, carbon dioxide, cholesterol, as H.sub.2 O.sub.2 liberating systems coupled to a tris(bipyridyl)ruthenium(II) Ru(bpy).sub.3.sup.2+ luminophore generate an ECL signal, which can be detected spectrophotometrically or electrochemically. The H.sub.2 O.sub.2 present reacts with oxalate in the presence of Ru(bpy).sub.3.sup.2+ to give an ECL response.

REFERENCES:
patent: 5308754 (1994-05-01), Kankare et al.
patent: 5527710 (1996-06-01), Nacamulli et al.
Jameison et al., Anal. Chem., vol. 68, pp. 1298-1302, (1996).
Kazakov et al., Chemical Abstracts 88:81303, Abstract of Opt. Spek Trosk, vol. 43, No. 6, pp. 1081-1085, (1977).
Rubenstein et al., J. Am. Chem. Soc., vol. 103, pp. 512-516, (1981).

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